_Zinc chloride_ (ZnCl₂) is formed by heating zinc in presence of
chlorine. It is obtained pure by dissolving pure zinc in hydrochloric
acid and treating this solution with chlorine. Zinc chloride is
obtained on the large scale by dissolving furnace calamine (zinc
oxide) in hydrochloric acid. Zinc chloride is corrosive. It is used
for impregnating wood and in weighting goods. Besides possible injury
to health from chlorine and hydrogen chloride, risk of arseniuretted
hydrogen poisoning is present in the manufacture if the raw materials
contain arsenic. Eulenburg considers that in soldering oppressive zinc
chloride fumes may come off if the metal to be soldered is first wiped
with hydrochloric acid and then treated with the soldering iron.
_Rock salt._—Mention may be made that even to salt in combination with
other chlorides (calcium chloride, magnesium chloride, &c.) injurious
effects are ascribed. Ulcers and perforation of the septum of the nose in
salt-grinders and packers who were working in a room charged with salt
dust are described.[8] These effects are similar to those produced by the
bichromates.
Organic Chlorine Compounds
_Carbon oxychloride_ (COCl₂, carbonyl dichloride, phosgene) is produced
by direct combination of chlorine and carbonic oxide in presence of
animal charcoal. Phosgene is itself a very poisonous gas which, in
addition to the poisonous qualities of carbonic oxide (which have to be
borne in mind in view of the method of manufacture), acts as an irritant
of the mucous membranes. Commercially it is in solution in toluene and
xylene, from which the gas is readily driven off by heating. It is used
in the production of various colours, such as crystal violet, Victoria
blue, auramine, &c.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account