To free the nitric acid of the accompanying lower oxides of nitrogen
(as well as chlorine, compounds of chlorine and other impurities) air
is blown into the hot acid. The mixture of sodium sulphate and sodium
bisulphate remaining in the retorts is either converted into sulphate by
addition of salt or used in the manufacture of glass.
The nitric acid obtained is used either as such or mixed with sulphuric
acid or with hydrochloric acid.
Pure nitric acid cannot at ordinary atmospheric pressure be distilled
unaltered, becomes coloured on distillation, and turns red when exposed
to light. It is extremely dangerous to handle, as it sets light to straw,
for example, if long in contact with it. It must be packed, therefore, in
kieselguhr earth, and when in glass carboys forwarded only in trains for
transport of inflammable material.
Red, _fuming nitric acid_, a crude nitric acid, contains much nitrous
and nitric oxides. It is produced if in the distillation process less
sulphuric acid and a higher temperature are employed or (by reduction) if
starch meal is added.
The successful production of nitric acid from the air must be referred
to. It is effected by electric discharges in special furnaces from which
the air charged with nitrous gas is led into towers where the nitric
oxide is further oxidised (to tetroxide), and finally, by contact with
water, converted into nitric acid.
Nitric acid is used in the manufacture of phosphoric acid, arsenious
acid, and sulphuric acid, nitro-glycerin and nitrocellulose, smokeless
powder, &c. (see the section on Explosives), in the preparation of
nitrobenzenes, picric acid, and other nitro-compounds (see Tar Products,
&c.). The diluted acid serves for the solution and etching of metals,
also for the preparation of nitrates, such as the nitrates of mercury,
silver, &c.
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