Thus, in a cellar were five large iron vessels containing a mixture of
sulphuric and nitric acids. One of the vessels was found one morning to
be leaking. The manager directed that smoke helmets should be fetched,
intending to pump out the acid, and two plumbers went into the cellar
to fix the pump, staying there about twenty-five minutes. They used
cotton waste and handkerchiefs as respirators, but did not put on the
smoke helmets. One plumber suffered only from cough, but the other died
the same evening with symptoms of great dyspnœa. At the autopsy severe
inflammation and swelling of the mucous membrane of the palate, pharynx
and air passages, and congestion of the lungs were found.
Two further fatal cases in the nitrating room are described by Holtzmann.
One of the two complained only a few hours after entering the room of
pains in the chest and giddiness. He died two days later. The other died
the day after entering the factory, where he had only worked for three
hours. In both cases intense swelling and inflammation of the mucous
membrane was found.
Holtzmann mentions cases of poisoning by nitrous fumes in the heating of
an artificial manure consisting of a mixture of saltpetre, brown coal
containing sulphur, and wool waste. Fatalities have been reported in
workers who had tried to mop up the spilt nitric acid with shavings.[3]
We quote the following other instances[4]:
(1) Fatal poisoning of a fireman who had rescued several persons from a
room filled with nitrous fumes the result of a fire occasioned by the
upsetting of a carboy. The rescued suffered from bronchial catarrh, the
rescuer dying from inflammation and congestion of the lungs twenty-nine
hours after the inhalation of the gas.
(2) At a fire in a chemical factory three officers and fifty-seven
firemen became affected from inhalation of nitrous fumes, of whom one
died.
(3) In Elberfeld on an open piece of ground fifty carboys were stored.
One burst and started a fire. As a strong wind was blowing the firemen
were little affected by the volumes of reddish fumes. Soon afterwards at
the same spot some fifty to sixty carboys were destroyed. Fifteen men
successfully extinguished the fire in a relatively still atmosphere in
less than half an hour. At first hardly any symptoms of discomfort were
felt. Three hours later all were seized with violent suffocative attacks,
which in one case proved fatal and in the rest entailed nine to ten days’
illness from affection of the respiratory organs.
The Report of the Union for Chemical Industry for 1908 describes a
similar accident in a nitro-cellulose factory.
Of those engaged in extinguishing the fire twenty-two were affected, and
in spite of medical treatment and use of the oxygen apparatus three died.
From the same source we quote the following examples:
Public-domain text, read in full here on John Shaqi.
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