A further source of artificial manure is _basic slag_—the slag left in
the manufacture of steel by the Gilchrist-Thomas method—which contains
10-25 per cent. of readily soluble phosphoric acid. It requires,
therefore, only to be ground into a very fine powder to serve as a
suitable manure.
Owing to the considerable heat generated by the action of the sulphuric
acid when mixed with the pulverised raw materials (especially in the
conversion of the phosphorites) hydrofluoric and silicofluoric acid
vapours are evolved in appreciable amount, and also carbonic and
hydrochloric acid vapours, sulphur dioxide, and sulphuretted hydrogen
gas. These gases—notably such as contain fluorine—if not effectually
dealt with by air-tight apparatus and exhaust ventilation—may lead to
serious annoyance and injury to the persons employed. Further, there is
risk of erosion of the skin from contact with the acid, &c.
A case is described of pustular eczema on the scrotum of a worker engaged
in drying sodium silicofluoride, due probably to conveyance of irritating
matter by the hands. After the precaution of wearing gloves was adopted
the affection disappeared.
A marked case of poisoning by nitrous fumes even is recorded in the
manufacture of artificial manure from mixing Chili saltpetre with a very
acid superphosphate.
Injurious fumes can be given off in the rooms where bones are stored and,
in the absence of efficient ventilation, carbonic acid gas can accumulate
to an amount that may be dangerous.
The fine dust produced in the grinding of _basic slag_ has, if inhaled, a
markedly corrosive action on the respiratory mucous membrane attributed
by some to the high proportion (about 50 per cent.) in it of quicklime.
As a matter of fact numerous small ulcers are found on the mucous
membranes of basic slag grinders and ulceration of the lung tissue has
been observed. The opinion is expressed that this is due to corrosive
action of the dust itself, and not merely to the sharp, jagged edged
particles of dust inhaled. And in support of this view is cited the
frequency with which epidemics of pneumonia have been noted among
persons employed in basic slag works. Thus in Nantes thirteen cases of
severe pneumonia followed one another in quick succession. And similar
association has been noted in Middlesbrough, where the action of the
basic slag dust was believed to injure the lung tissue and therefore to
provide a favourable soil for the development of the pneumonia bacillus.
Statistics collected by the Imperial Health Office showed that in the
three years 1892, 1893, and 1894, 91·1 per cent., 108·9 per cent., and
91·3 per cent. respectively of the workers became ill, the proportion
of respiratory diseases being 56·4 per cent., 54·4 per cent., and 54·3
per cent. respectively. A case of severe inflammation of the lungs is
described in a labourer scattering basic slag in a high wind which drove
some of it back in his face.
Public-domain text, read in full here on John Shaqi.
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