EFFECTS ON HEALTH.—Injury to health from work at coke ovens is similar
to that in the manufacture of illuminating gas. There is the possibility
of carbonic oxide poisoning from escape of gas from leakage in the
apparatus. As further possible sources of danger ammonia, cyanogen and
sulpho-cyanogen compounds, and benzene have to be borne in mind.
In the distillation of the wash oil severe poisoning can arise, as in a
case described, where two men were fatally poisoned in distilling tar
with wash oil.[1]
The details of the case are not without interest. The poisoning occurred
in the lavatory. The gases had escaped from the drain through the
ventilating shaft next to the closet. The gases came from distillation of
the mixture of tar and wash oil, and were driven by means of air pumps
in such a way that normally the uncondensed gases made their way to the
chimney stack. On the day of the accident the pumps were out of use, and
the gases were driven by steam injectors into the drain. Analysis showed
the gases to contain much sulphuretted hydrogen. When this was absorbed,
a gas which could be condensed was obtained containing carbon bisulphide
and hydrocarbons of unknown composition (? benzene). Only traces of
cyanogen and sulpho-cyanogen compounds were present. Physiological
experiment showed that poisoning was attributable mainly to sulphuretted
hydrogen gas, but that after this was removed by absorption a further
poisonous gas remained.
Other Kinds of Power and Illuminating Gas
_Producer gas_ or _generator gas_.—Manufacture of producer gas consists
in dealing separately with the generation of the gas and the combustion
of the gases which arise. This is effected by admitting only so much air
(primary air supply) to the fuel as is necessary to cause the gases to
come off, and then admitting further air (secondary supply) at the point
where the combustion is to take place; this secondary supply and the gas
formed in the gas producer are heated in regenerators before combustion
by bringing the gases to be burnt into contact with _Siemens’s heaters_,
of which there are four. Two of these are always heated and serve to heat
the producer gas and secondary air supply.
[Illustration: FIG. 15.—Horizontal Regenerative Grate (_after Lueger_)]
A producer gas furnace, therefore, consists of a gas producer, a gas main
leading to the furnace hearth, the heater, and the chimney.
[Illustration: FIG. 16.—Step Regenerative Grate (_after Lueger_)]
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