The furnaces used in the production of calcium carbide are of different
construction. Generally the furnace is of the nature of an electric arc,
and is arranged either as a crucible furnace for intermittent work or
like a blast furnace for continuous work.
Besides these there are resistance furnaces in which the heat is created
by the resistance offered to the passage of the current by the molten
calcium carbide.
The carbonic oxide given off in the process causes difficulty. In many
furnaces it is burnt and so utilised for heating purposes. The calcium
carbide produced contains as impurities silicon carbide, ferro-silicon,
calcium sulphide, and calcium phosphide.
_Acetylene_ (C₂H₂), formed by the decomposition of calcium carbide by
means of water (CaC₂ + 2H₂O = Ca(OH)₂ + C₂H₂), furnishes when pure an
illuminating gas of great brilliancy and whiteness. Its production is
relatively easy. Used for the purpose are (1) apparatus in which water
is made to drop on the carbide, (2) apparatus in which the carbide dips
into water and is removed automatically on generation of the gas, (3)
apparatus in which the carbide is completely immersed in water, and (4)
apparatus in which the carbide in tiny lumps is thrown on to water. These
are diagrammatically represented in figs. 20A to 20D.
[Illustration: FIG. 20A.
FIG. 20B.
FIG. 20C.
FIG. 20D.
Acetylene Apparatus—diagrammatic (_after Lueger_) A Dripping; B Dipping;
C Submerging; D Throwing in]
The most important impurities of acetylene are ammonia, sulphuretted
hydrogen gas, and phosphoretted hydrogen. Before use, therefore, it
is subjected to purification in various ways. In Wolf’s method the
gas is passed through a washer (with the object of removing ammonia
and sulphuretted hydrogen gas) and a purifying material consisting
of chloride of lime and bichromate salts. In Frank’s method the gas
passes though a system of vessels containing an acid solution of copper
chloride, and also through a washer. Chloride of lime with sawdust is
used as a purifying agent. Finally, the gas is stored and thence sent to
the consumer (see fig. 21).
[Illustration: FIG. 21.—Acetylene Gas Apparatus (_after Lueger_)]
EFFECTS ON HEALTH.—Almost all the poisoning caused in the industries in
question is due to carbonic oxide gas, of which water gas contains 41 per
cent., generator gas 35 per cent., and suction and Dowson gas 25 per cent.
That industrial carbonic oxide poisoning is not rare the reports of the
certifying surgeons in Great Britain sufficiently show. In the year 1906
fifty-five persons are referred to as having suffered, with fatal issue
in four. In 1907 there were eighty-one, of which ten were fatal. Of the
1906 cases twenty resulted from inhalation of producer, Mond, or suction
gas, sixteen from coal gas (in several instances containing carburetted
water gas), seventeen from blast furnace gas, and one each from charcoal
fumes from a brazier, and from the cleaning out of an oil gas holder.
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