In reference to the cases which occurred in rubber factories it is
conceivable that carbon bisulphide played a part, since in such factories
not only are mixtures of benzol and carbon bisulphide used, but also
frequently the ‘first runnings’ of benzol, which, on account of the high
proportion (sometimes 50 per cent.) of carbon bisulphide in them, make an
excellent solvent for rubber.
From some coke ovens crude benzol was collected in two large iron
receivers. They were sunk in a pit projecting very little above the
ground. To control the valves the workmen had to mount on the receiver,
the manholes of which were kept open during filling. The pit was roofed
over and two wooden shafts served both for ventilation and as approaches
to the valves. One summer day benzol had been blown in the usual way
into a railway truck and a worker had entered the space to control the
valves. Some time afterwards he was found in a doubled-up position on
the receiver, grasping the valves, from which later he fell off down to
the bottom of the pit. Three rescuers entered, but had to retire as they
became affected. A fourth worker, in the presence of the manager, was let
down by a rope, but succumbed immediately and was dragged up a corpse.
Finally, equipped with a smoke helmet, a rescuer brought up the lifeless
body of the first man. It was believed that the benzol had distilled
over warm and had evaporated to such an extent as to fill with fumes the
unsuitably arranged and inadequately ventilated space. Possibly other
volatile compounds were responsible for the poisoning.[3]
A similar though less serious accident occurred to a foreman who forgot
to set the cooling apparatus at work at the commencement of distillation,
and became unconscious from the escaping fumes, as also did a rescuer.
The latter was brought round by oxygen inhalation, but the former,
although alive when recovered, succumbed despite efforts at artificial
respiration.
A fatal case occurred in an aniline factory where benzol fumes had
escaped owing to faulty arrangement of the valves. The worker, although
ordered at once to leave the room, was found there ten minutes later dead.
Interesting are the following cases of accidents due to use of paints
containing benzol.
In painting a retort with an anti-corrosive paint called ‘Original
Anti-corrosive,’ unconsciousness followed on completion of the painting,
but by prompt rescue and medical assistance life was saved. The accident
was attributed to benzol fumes from the paint insufficiently diluted by
the air coming in at the open manhole. A similar case arose from use
of a rust-preventing paint—‘Preolith’—and only with difficulty was the
man using it pulled out from the inside of the steam boiler. Although
resuscitated by oxygen inhalation, he was incapacitated for eight days.
Crude benzol was a constituent of ‘Preolith.’ Obviously use of such
paints in closely confined spaces is very risky.
Public-domain text, read in full here on John Shaqi.
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