A similar case of benzene poisoning occurred in a naphthalamine works
through inspecting an extracting vessel which had contained benzene
and naphthalamine and had to be cleaned. The vessel had been empty for
twenty-two hours and had been washed and ventilated, but through a
leaking pipe benzene had dropped down into it. The workman engaged was
rendered unconscious inside the retort, but was rescued by an engineer
equipped with a breathing helmet. Others who without such apparatus tried
to effect a rescue were overcome, and one who had entered the retort
succumbed.[1]
Benzene poisoning has often occurred in the cleaning of tanks, &c., for
the transport and storage of the substance. The following examples are
taken from the Reports of the Union of Chemical Industry.
A worker during the pause for breakfast had, unknown to his employer,
cleaned out an empty truck for crude benzol. Later he was with difficulty
removed unconscious through the manhole and could not be resuscitated.
Only a short time previously a similar occurrence had taken place in the
same factory.
Two further fatal cases were reported in 1908 in the cleaning out of
railway tank waggons. The tank had previously been thoroughly sprayed
with water. The partition plates which are required in such tanks
increase the difficulty of cleaning from the manhole. After the foreman
had tested the air by putting his head inside and considered it free from
danger, a man entered to clean out the deposit; another man on watch
outside had evidently gone in for rescue purposes. Resuscitation in both
cases failed.
A worker died and several were affected in the cleaning out of a benzol
storage tank in a tar distillery. The tank had had air blown through it
several weeks before, and had been thoroughly cleaned by steam and water.
Also in the inspection the greatest care was taken in only permitting
work for short spells. This shows that, notwithstanding great care, the
last traces of benzol cannot be entirely removed and that quite small
quantities are sufficient to cause severe and even fatal poisoning.
Workers should only clean out tanks, therefore, when properly equipped
with helmets.
In the German factory inspectors’ reports for 1902 a case of intoxication
is described in a man who was engaged painting the inside of an iron
reservoir with an asphalt paint dissolved in benzol.
Of special interest is a fatal case from inhalation of benzol fumes in
a rubber factory. Rubber dissolved in benzol was being rubbed into the
cloth on a spreading machine in the usual way. The cloth then passes
under the cleaning doctor along the long heated plate to the end rolls.
Of the three men employed at the process one was found to be unconscious
and could not be brought round again.
The cases described[2] of poisoning with impure benzol in a pneumatic
tyre factory in Upsala are, perhaps, analogous. Here nine young women had
severe symptoms, four of whom died.
Public-domain text, read in full here on John Shaqi.
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