James Clerk Maxwell and Modern PhysicsGlazebrook, Richard
History
James Clerk Maxwell and Modern Physics
Glazebrook, Richard
Maxwell, James Clerk, 1831-1879; Physics -- History
By the time the first edition of the “Electricity and Magnetism”
was published, Maxwell and Thomson (Lord Kelvin) had both made
determinations of K, and had shewn that for air at least the resulting
value for the velocity of electro-magnetic waves was very nearly that
of light.
For other substances at that date the observations were fewer still.
Gibson and Barclay had determined the specific inductive capacity
of paraffin, and found that its square root was 1·405, while its
refractive index for long waves is 1·422. Maxwell himself thought
that if a similar agreement could be shewn to hold for a number of
substances, we should be warranted in concluding that “the square root
of K, though it may not be the complete expression for the index of
refraction, is at least the most important term in it.”
Between this time and Maxwell’s death enough had been done to more
than justify this statement. It was clear from the observations of
Boltzmann, Silow, Hopkinson, and others that there were many substances
for which the square root of the specific inductive capacity was very
nearly indeed equal to the refractive index, and good reason had been
given why in some cases there should be a considerable difference
between the two.
Hopkinson found that in the case of glass the differences were very
large, and they have since been found to be considerable for most
solids examined, with the exception of paraffin and sulphur. For
petroleum oil, benzine, toluene, carbon-bisulphide, and some other
liquids the agreement between Maxwell’s theory and experiment is
close. For the fatty oils, such as castor oil, olive oil, sperm oil,
neatsfoot oil, and also for ether, the differences are considerable.
It seems probable that the reason for this difference lies in the
fact that, in the light waves, we are dealing with the wave velocity
of a disturbance of an extremely short period. Now, we know that the
substances mentioned shew optical dispersion, and we have at present
no completely satisfactory theory from which we can calculate, from
experiments on very short waves, what the velocity for very long
waves will be. In most cases Cauchy’s formula has been used to obtain
the numbers given. The value of K, however, as found by experiment,
corresponds to these infinitely long waves, and to quote Professor
J. J. Thomson’s words, “the marvel is not that there should not be
substances for which the relation K = μ² does not hold, but that there
should be any for which it does.”[66]
Public-domain text, read in full here on John Shaqi.
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