James Clerk Maxwell and Modern PhysicsGlazebrook, Richard
History
James Clerk Maxwell and Modern Physics
Glazebrook, Richard
Maxwell, James Clerk, 1831-1879; Physics -- History
It follows also from the investigation that, on the hypotheses assumed
as its basis, if two kinds of gases be mixed, the difference between
the average kinetic energies of translation of the gases of each kind
diminishes rapidly in consequence of the action between the two. The
average kinetic energy of translation, therefore, tends to become the
same for each kind of gas, and as before, it is this average energy of
translation which measures the temperature.
A molecule in the theory is a portion of a gas which moves about as a
single body. It may be a mere point, a centre of force having inertia,
capable of doing work while losing velocity. There may be also in each
molecule systems of several such centres of force bound together by
their mutual actions. Again, a molecule may be a small solid body of
determinate form; but in this case we must, as Maxwell points out,
introduce a new set of forces binding together the parts of each
molecule: we must have a molecular theory of the second order. In any
case, the most general supposition made is that a molecule consists of
a series of parts which stick together, but are capable of relative
motion among each other.
In this case the kinetic energy of the molecule consists of the energy
of its centre of gravity, together with the energy of its component
parts, relative to its centre of gravity.[53]
Now Clausius had, as we have seen, given reasons for believing that the
ratio of the whole energy of a molecule to the energy of translation of
its centre of gravity tends to become constant. We have already used β
to denote this constant. Thus, while the temperature is measured by the
average kinetic energy of translation of the centre of gravity of each
molecule, the heat contained in a molecule is its whole energy, and is
β times this quantity. Thus the conclusions as to specific heat, etc.,
already given on page 130, apply in this case, and in particular we
have the result that if γ be the ratio of the specific heat at constant
pressure to that at constant volume, then--
β = ⅔ 1/(γ-1)
Maxwell’s theorem of the distribution of kinetic energy among a system
of molecules applied, as he gave it in 1866, to the kinetic energy of
translation of the centre of gravity of each molecule. Two years later
Dr. Boltzmann, in the paper we have already referred to, extended
it (under certain limitations) to the parts of which a molecule is
composed. According to Maxwell the average kinetic energy of the centre
of gravity of each molecule tends to become the same. According to
Boltzmann the average kinetic energy of each part of the molecule tends
to become the same.
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