James Clerk Maxwell and Modern PhysicsGlazebrook, Richard
History
James Clerk Maxwell and Modern Physics
Glazebrook, Richard
Maxwell, James Clerk, 1831-1879; Physics -- History
Maxwell, in the last paper he wrote on the subject (“On Boltzmann’s
Theorem on the Average Distribution of Energy in a System of
Material Points,” Camb. Phil. Trans., XII.), took up this problem.
Watson had given a proof of it in 1876 differing from Boltzmann’s,
but still limited by the stipulation that the time, during which a
particle is encountering other particles, is very small compared with
the time during which there is no sensible action between it and
other particles, and also that the time during which a particle is
simultaneously within the distance of more than one other particle may
be neglected.
Maxwell claims that his proof is free from any such limitation. The
material points may act on each other at all distances, and according
to any law which is consistent with the conservation of energy; they
may also be acted on by forces external to the system, provided these
are consistent with that law.
The only assumption which is necessary for the direct proof is that
the system, if left to itself in its actual state of motion, will
sooner or later pass through every phase which is consistent with the
conservation of energy.
In this paper Maxwell finds in a very general manner an expression for
the number of molecules which at any time have a given velocity, and
this, when simplified by the assumptions of the former papers, reduces
to the form already found. He also shows that the average kinetic
energy corresponding to any one of the variables which define his
system is the same for every one of the variables of his system.
Thus, according to this theorem, if each molecule be a single small
solid body, six variables will be required to determine the position
of each, three variables will give us the position of the centre of
gravity of the molecule, while three others will determine the position
of the body relative to its centre of gravity. If the six variables
be properly chosen, the kinetic energy can be expressed as a sum of
six squares, one square corresponding to each variable. According to
the theorem the part of the kinetic energy depending on each square is
the same. Thus, the whole energy is six times as great as that which
arises from any one of the variables. The kinetic energy of translation
is three times as great as that arising from each variable, for it
involves the three variables which determine the position of the centre
of gravity. Hence, if we denote by K the kinetic energy due to one
variable, the whole energy is 6 K, and the translational energy is 3 K;
thus, for this case--
β = 6K/3K = 2
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