James Clerk Maxwell and Modern PhysicsGlazebrook, Richard
History
James Clerk Maxwell and Modern Physics
Glazebrook, Richard
Maxwell, James Clerk, 1831-1879; Physics -- History
Or, again, if we suppose that the molecule is such that _m_ variables
are required to determine its position relatively to its centre of
gravity, since 3 are needed to fix the centre of gravity, the total
number of variables defining the position of the molecule is _m_ + 3,
and it is said to have _m_ + 3 degrees of freedom. Hence, in this case,
its total energy is (_m_ + 3) K and its energy of translation is 3 K,
thus we find--
β = (_m_ + 3)/3
Hence γ = 1 + 2/(_m_ + 3) = 1 + 2/_n_
if _n_ be the number of degrees of freedom of the molecule.
Thus, if this Boltzmann-Maxwell theorem be true, the specific heat of a
gas will depend solely on the number of degrees of freedom of each of
its molecules. For hard rigid bodies we should have _n_ equal to 6, and
hence γ = 1·333. Now the fact that this is not the value of γ for any
of the known gases is a fundamental difficulty in the way of accepting
the complete theory.
Boltzmann has called attention to the fact that if _n_ be equal to
five, then γ has the value 1·40. And this agrees fairly with the value
found by experiment for air, oxygen, nitrogen, and various other gases.
We will, however, return to this point shortly.
There is, perhaps, no result in the domain of physical science in
recent years which has been more discussed than the two fundamental
theorems of the molecular theory which we owe to Maxwell and to
Boltzmann.
The two results in question are (1) the expression for the number of
molecules which at any moment will have a given velocity, and (2) the
proposition that the kinetic energy is ultimately equally divided
among all the variables which determine the system.
With regard to (1) Maxwell showed that his error law was one possible
condition of permanence. If at any moment the velocities are
distributed according to the error law, that distribution will be a
permanent one. He did not prove that such a distribution is the only
one which can satisfy all the conditions of the problem.
The proof that this law is a necessary, as well as a sufficient,
condition of permanence was first given by Boltzmann, for a single
monatomic gas in 1872, for a mixture of such gases in 1886, and for a
polyatomic gas in 1887. Other proofs have been given since by Watson
and Burbury. It would be quite beyond the limits of this book to go
into the question of the completeness or sufficiency of the proofs. The
discussion of the question is still in progress.
The British Association Report for 1894 contains an important
contribution to the question, in the shape of a report by Mr. G. H.
Bryan, and the discussion he started at Oxford by reading this report
has been continued in the pages of _Nature_ and elsewhere since that
time.
Mr. Bryan shows in the first place what may be the nature of the
systems of molecules to which the results will apply, and discusses
various points of difficulty in the proof.
Public-domain text, read in full here on John Shaqi.
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