James Clerk Maxwell and Modern PhysicsGlazebrook, Richard
History
James Clerk Maxwell and Modern Physics
Glazebrook, Richard
Maxwell, James Clerk, 1831-1879; Physics -- History
The Boltzmann-Maxwell law applies only to cases in which the
temperature is uniform throughout. In a paper published in the
Philosophical Transactions for 1879, on “Stresses in Rarefied Gases
Arising from Inequalities of Temperature,” Maxwell deals, among other
matters, with the theory of the radiometer. He shows that the observed
motions will not take place unless gas, in contact with a solid, can
slide along the surface of the solid with a finite velocity between
places where the temperature is different; and in an appendix he proves
that, on certain assumptions regarding the nature of the contact of the
solid and the gas, there will be, even when the pressure is constant, a
flow of gas along the surface from the colder to the hotter parts.
Among his less important papers bearing on molecular theory must be
mentioned a lecture on “Molecules” to the British Association at its
Bradford meeting; “Scientific Papers of Clerk Maxwell,” vol. ii., p.
361; and another on “The Molecular Constitution of Bodies,” Scientific
Papers, vol. ii., p. 418.
In this latter, and also in a review in _Nature_ of Van der Waals’
book on “The Continuity of the Gaseous and Liquid States,”[56] he
explains and discusses Clausius’ virial equation, by means of which the
variations of the permanent gases from Boyle’s law are explained. The
lecture gives a clear account, in Maxwell’s own inimitable style, of
the advances made in the kinetic theory up to the date at which it was
delivered, and puts clearly the difficulties it has to meet. Maxwell
thought that those arising from the known values of the ratio of the
specific heats were the most serious.
In the articles, “Atomic Constitution of Bodies” and “Diffusion,” in
the ninth edition of the _Encyclopædia Britannica_, we have Maxwell’s
later views on the fundamental assumptions of the molecular theory.
The text-book on “Heat” contains some further developments of the
theory. In particular he shows how the conclusions of the second law
of thermo-dynamics are connected with the fact that the coarseness of
our faculties will not allow us to grapple with individual molecules.
The work described in the foregoing chapters would have been sufficient
to secure to Maxwell a distinguished place among those who have
advanced our knowledge; it remains still to describe his greatest work,
his theory of Electricity and Magnetism.
CHAPTER IX.
SCIENTIFIC WORK.--ELECTRICAL THEORIES.
Clerk Maxwell’s first electrical paper--that on Faraday’s “Lines of
Force”--was read to the Cambridge Philosophical Society on December
10th, 1855, and Part II. on February 11th, 1856. The author was then a
Bachelor of Arts, only twenty-three years in age, and of less than one
year’s standing from the time of taking his degree.
The opening words of the paper are as follows (Scientific Papers, vol.
i., p. 155):--
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