“I put some bits of charcoal into my phial instead of the oil or other inflammable matter which I had used before, and applying the flame of a candle I presently found that the vitriolic acid air was produced as well as in the former process, and in several respects more conveniently, the production of air being equable, whereby the disagreeable effect of a sudden explosion is avoided.... Finding that a great variety of substances containing phlogiston enabled the oil of vitriol to throw out a permanent acid air, I had some suspicion that mere _heat_ might do the same, but I did not find that there was any foundation for that suspicion.... But though I got no air from the oil of vitriol by this process, air was produced at the same time in a manner that I little expected, and I paid pretty dearly for the discovery it occasioned. Despairing to get any air from the longer application of my candles, I withdrew them, but before I could disengage the phial from the vessel of quicksilver a little of it passed through the tube into the hot acid, when instantly it was all filled with dense white fumes, a prodigious quantity of air was generated, the tube through which it was transmitted was broken into many pieces, and part of the hot acid being spilled upon my hand burned it terribly, so that the effect of it is visible to this day. The inside of the phial was coated with a white saline substance, and the smell that issued from it was extremely suffocating. “This accident taught me what I am surprised I should not have suspected before, viz., that some _metals_ will part with their phlogiston to hot oil of vitriol, and thereby convert it into a permanent elastic air, producing the very same effect with oil, charcoal, or any other inflammable substance. “Not discouraged by the disagreeable accident above mentioned, the next day I put a little _quicksilver_ into the phial with the ground stopple and tube, along with the oil of vitriol, when, long before it was boiling hot, air issued plentifully from it, and being received in a vessel of quicksilver appeared to be genuine vitriolic acid air, exactly like that which I had procured before, being readily imbibed by water and extinguishing a candle in the same manner as the other had done.... “After this I repeated the experiment with several other metals.... Copper treated in the same manner yielded air very freely, with about the same degree of heat that quicksilver had required, and the air continued to be generated with very little application of more heat.”