Chemists -- England -- Biography; Priestley, Joseph, 1733-1804
“But having afterwards procured a lens of twelve inches diameter and
twenty inches focal distance, I proceeded with great alacrity to
examine, by the help of it, what kind of air a great variety of
substances, natural and factitious, would yield, putting them into
vessels [short, wide, round-bottomed phials], which I filled with
quicksilver and kept inverted in a basin of the same. Mr Warltire, a
good chemist, and lecturer in Natural Philosophy, happening to be at
that time in Calne, I explained my views to him, and was furnished by
him with many substances, which I could not otherwise have procured.
“With this apparatus, after a variety of other experiments, an account
of which will be found in its proper place on the 1st August 1774, I
endeavoured to extract air from _mercurius calcinatus per se_;[17] and
I presently found that, by means of this lens, air was expelled from
it very readily. Having got about three or four times as much as the
bulk of my materials, I admitted water to it, and found that it was
not imbibed by it. But what surprised me more than I can well express
was that a candle burned in this air with a remarkably vigorous flame,
very much like that enlarged flame with which a candle burns in
nitrous air exposed to iron or liver of sulphur,[18] but as I had got
nothing like this remarkable appearance from any kind of air besides
this particular modification of nitrous air, and I knew no nitrous
acid was used in the preparation of mercurius calcinatus, I was
utterly at a loss how to account for it.
“In this case also, though I did not give sufficient attention to the
circumstance at that time, the flame of the candle, besides being
larger, burned with more splendour and heat than in that species of
nitrous air; and a piece of red-hot wood sparkled in it, exactly like
paper dipped in a solution of nitre, and it consumed very fast; an
experiment which I had never thought of trying with nitrous air.
“At the same time that I made the above-mentioned experiment I
extracted a quantity of air with the very same property from the
common _red precipitate_[19] which, being produced by a solution of
mercury in spirit of nitre (nitric acid), made me conclude that this
peculiar property, being similar to that of the modification of
nitrous air above mentioned, depended upon something being
communicated to it by the nitrous acid; and since the _mercurius
calcinatus_ is produced by exposing mercury to a certain degree of
heat, where common air has access to it, I likewise concluded that
this substance had collected something of _nitre_, in that state of
heat, from the atmosphere.
Public-domain text, read in full here on John Shaqi.
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