Chemists -- England -- Biography; Priestley, Joseph, 1733-1804
“This, however, appearing to me much more extraordinary than it ought
to have done, I entertained some suspicion that the mercurius
calcinatus on which I had made my experiments, being bought at a
common apothecary’s, might, in fact, be nothing more than red
precipitate; though, had I been anything of a practical chemist, I
could not have entertained any such suspicion. However, mentioning
this suspicion to Mr Warltire, he furnished me with some that he had
kept for a specimen of the preparation, and which, he told me, he
could warrant to be genuine. This being treated in the same manner as
the former, only by a longer continuance of heat, I extracted much
more air from it than from the other.
“This experiment might have satisfied any moderate sceptic; but,
however, being at Paris in the October following, and knowing that
there were several very eminent chemists in that place, I did not omit
the opportunity, by means of my friend Mr Magellan, to get an ounce of
mercurius calcinatus prepared by Mr Cadet, of the genuineness of which
there could not possibly be any suspicion; and at the same time I
frequently mentioned my surprise at the kind of air which I had got
from this preparation to Mr Lavoisier, Mr le Roy, and several other
philosophers, who honoured me with their notice in that city, and who,
I daresay, cannot fail to recollect the circumstance.”
This last remark is significant in reference to a claim which was
subsequently put forward that the real discoverer of oxygen was
Lavoisier, and that he obtained it by heating mercuric oxide.[20]
Priestley also obtained the same air from _red lead_, which, he says,
“confirmed me more in my suspicion that the _mercurius calcinatus_
must get the property of yielding this kind of air from the
atmosphere, the process by which that preparation and this of red lead
is made being similar. As I never make the least secret of anything
that I observe, I mentioned this experiment also, as well as those
with the mercurius calcinatus and the red precipitate, to all my
philosophical acquaintance at Paris and elsewhere, having no idea, at
that time, to what these remarkable facts would lead.” [Nitrous
oxide.]
Priestley, on his return to England, made an experiment with Cadet’s
preparation, which he found to behave precisely like that he had
procured from Warltire. He observed that the new gas was only sparingly
soluble in water and that its power of causing a candle to burn with a
strong flame was in nowise diminished by agitation with water—facts
which he said convinced him
“that there must be a very material difference between the
constitution of the air from mercurius calcinatus and that of
phlogisticated nitrous air, [nitrous oxide] notwithstanding their
resemblance in some particulars.”
Public-domain text, read in full here on John Shaqi.
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