Chemists -- England -- Biography; Priestley, Joseph, 1733-1804
It was not, however, until the following March (1775) (he having
meanwhile been intent upon his experiments on the vitriolic air [sulphur
dioxide]), that he ascertained the real nature of the new air, and was
led “though very gradually ... to the complete discovery of the
constitution of the air we breathe.” By trials with the nitrous air and
with mice he found that the new gas was eminently fit for respiration:
nitrous air reduced its volume to a greater extent than in the case of
common air, and a mouse lived longer in it than it would in the same
volume of common air.
“Thinking of this extraordinary fact upon my pillow, the next morning
I put another measure of nitrous air to the same mixture, and to my
utter astonishment found that it was farther diminished to almost
one-half of its original quantity.”
Priestley now utterly missed his way for a time. He sought to get the
new air from the various oxides of lead, but the fetish of phlogiston
again led him wrong, and eventually by a train of reasoning which is
fully set forth in the paper, but which need not here be repeated, there
remained, he says, no doubt in his mind
“but that _atmospherical air_, or the thing that we breathe, _consists
of the nitrous acid and earth_, with so much phlogiston as is
necessary to its elasticity; and likewise so much more as is required
to bring it from its state of perfect purity to the mean condition in
which we find it.”
Priestley’s “complete discovery of the constitution of the air we
breathe” was thus wholly erroneous: he was very far indeed from having a
clear conception of its real nature.
Priestley’s description of the main properties of oxygen is however
accurate, and lecturers in chemistry are indebted to him for some
striking experimental illustrations of them.
“I easily conjectured,” he says, “that inflammable air would explode
with more violence and a louder report by the help of dephlogisticated
than of common air; but the effect far exceeded my expectations, and
it has never failed to surprise every person before whom I have made
the experiment.... The dipping of a lighted candle into a jar filled
with dephlogisticated air is alone a very beautiful experiment. The
strength and vivacity of the flame is striking, and the heat produced
by the flame in these circumstances is also remarkably great....
Nothing would be easier than to augment the force of fire to a
prodigious degree by blowing it with dephlogisticated air instead of
common air.... Possibly _platina_ might be melted by means of it.
Public-domain text, read in full here on John Shaqi.
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