Chemists -- England -- Biography; Priestley, Joseph, 1733-1804
“Fluctuating, however, as the present state of this branch of
knowledge is, I do not think that I can, on this occasion, entirely
decline giving some observations of a theoretical nature, and though I
cannot pretend to perform the whole of my promise, I shall give a
summary view of what appears to me to be the constituent parts of all
the kinds of air with which we are acquainted, and a more particular
account of the hypothesis concerning phlogiston, which is at present
more an object of discussion than anything else of a theoretical
nature.”
Priestley then passes in review all the “airs” of which the chemistry of
his time had any knowledge, giving the _elements_ or constituent
principles of which he imagined them to be composed.
The only kind of air that he thinks to be properly _elementary_, and to
consist of a simple substance, is _dephlogisticated air_, with possibly
the addition of the principle of heat, which, as it is not probable that
it adds to the _weight_ of bodies, can hardly be called an _element_ in
their composition.
“Dephlogisticated air appears to be one of the elements of water, of
fixed air, of all the acids, and of many other substances which, till
lately, have been thought to be simple. The air of the atmosphere,
exclusive of a great variety of foreign impregnations, appears to
consist of dephlogisticated and phlogisticated air.”
As regards _phlogisticated air_—the mephitic air of Rutherford, the
azote of Lavoisier, the nitrogen of Chaptal—Priestley, reasoning from
Cavendish’s work, concluded that it was probably not elementary, but
“that it consists of nitrous acid and phlogiston; this acid having
always been produced by decomposing it with ... dephlogisticated air.”
He is conscious, however, of the insufficiency of this hypothesis, and
suggests
“that the _acid principle_ is supplied by the dephlogisticated air,
while the nitrous air gives the base of the nitrous acid and
phlogiston; and then this [phlogisticated] air may perhaps be
considered as phlogiston combined not with all the necessary elements
of nitrous acid, but only what may be called the base of it, _viz._,
the dephlogisticated nitrous vapour, or something which when united to
dephlogisticated air will constitute nitrous acid.”
“_Fixed air_ (carbonic acid) seems to be a compound of phlogiston and
dephlogisticated air.” In other words, carbonic acid and water have,
according to Priestley, “the same elementary composition.” “It is
something remarkable that two substances so different from each other as
_fixed air_ and _water_ should be analysed into the same principles. But
there is this difference between them, that water is the union not of
pure phlogiston but of inflammable air and dephlogisticated air.”
Of the true nature of _inflammable air_, Priestley, as we have more than
once had occasion to point out, had only the vaguest notions.
Public-domain text, read in full here on John Shaqi.
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