Chemists -- England -- Biography; Priestley, Joseph, 1733-1804
“Inflammable air,” he says, “seems now to consist of water and
inflammable air, which however seems extraordinary, as the two
substances are hereby made to involve each other, one of the
constituent parts of water being inflammable air, and one of the
constituent parts of inflammable air being water; and therefore, if
the experiments would favour it (but I do not see that they do so) it
would be more natural to suppose that water, like fixed air, consists
of phlogiston and dephlogisticated air in some different mode of
combination.”
That Priestley to the last imagined that the various kinds of
inflammable air known to him were at bottom one and the same substance,
modified or affected by other substances, accidental and unessential,
might be proved by a number of passages. He says with respect to
inflammable air generally:—
“There is an astonishing variety in the different kinds of inflammable
air, the cause of which is very imperfectly known. The lightest, and
therefore, probably, the purest kind seems to consist of phlogiston
and water only. But it is probable that _oil_, and that of different
kinds, may be held in solution in several of them, and be the reason
of their burning with a lambent flame, and also of their being so
readily resolved into fixed air when they are decomposed with
dephlogisticated air; though _why_ this should be the case I cannot
imagine.”
_Nitrous air_ (nitric oxide) he conceives to be a combination of a
dephlogisticated nitrous air and phlogiston, and that by adding to it
dephlogisticated air and water it is converted into nitrous acid.
_Dephlogisticated nitrous air_ (nitrous oxide) he conceives may, like
dephlogisticated air, be an elementary substance and to be formed by
depriving nitrous air of its phlogiston.
The various _acid airs_ (_e.g._, marine acid air, vitriolic acid air,
etc.) consist of the peculiar acids as vapours combined with phlogiston.
The _Alkaline air_ (ammonia) he thought to consist of inflammable air
and phlogisticated air (nitrogen),
“or of something capable of being converted into phlogisticated
air.... That water enters into the composition of alkaline air seems
necessary to be admitted, because it is decomposed into inflammable
air, which I cannot help thinking necessarily requires water. It
seems, however, clearly to be inferred ... that there is no occasion
to admit the _alkaline principle_ into the number of _elements_; the
_alkalinity_, as I may say, some way or other, arising from
phlogiston, or phlogisticated air, as _acidity_ arises from
dephlogisticated air.”
Public-domain text, read in full here on John Shaqi.
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