Chemists -- England -- Biography; Priestley, Joseph, 1733-1804
After these theoretical speculations, “in which,” he says, “I fear I
have not communicated much light, though it is as much as I have been
able to get,” Priestley proceeds to make some observations relating to
_phlogiston_, “the existence of which is at present a great subject of
discussion with philosophers; some maintaining that there is no such
thing, and others holding the doctrine of Stahl on the subject.”
“According to Stahl, phlogiston is a real substance, capable of being
transferred from one body to another; its presence or absence making a
remarkable difference in the properties of bodies, whether it add to
their _weight_ or not. Thus he concluded that oil of vitriol deprived
of water, and united to phlogiston, becomes sulphur; and that the
calces of metals, by the addition of the same substance, become
metals.... What is now contended for is that in the oil of vitriol
changing into sulphur something is lost and nothing gained, and also
that a calx becomes a metal by the loss of air only. And did facts
correspond to this theory it would certainly be preferable to that of
Stahl, as being more simple; there being one principle less to take
into our account in explaining the changes of bodies. But I do not
know of any case in which phlogiston has been supposed to enter into a
body, but there is room to suppose that something does enter into
it....
“What has been insisted upon, as most favourable to the exclusion of
phlogiston, is the revival of mercury without the addition of any
other substance from the precipitate _per se_. In this case it is
evident that mere _heat_ ... is sufficient to revive the metal. And as
what is expelled from this calx is the purest dephlogisticated air, it
has been said that mercury is changed into this calx by imbibing pure
air, and therefore becomes a metal again, merely in consequence of
parting with that air.”
The dexterous Mr Kirwan, not long before he himself embraced the French
doctrine, furnished Priestley with an argument which satisfied him that
this cardinal fact can be accounted for without excluding phlogiston.
“Since therefore the supposition is exceedingly convenient, if not
absolutely necessary, to the explanation of many other facts in
chemistry, it is at least advisable not to abandon it.”
Public-domain text, read in full here on John Shaqi.
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