Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving riskLegge, Thomas Morison, Sir
Science
Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving risk
Legge, Thomas Morison, Sir
Lead poisoning
_Method of Fresenius and Von Babo[5]--Moist Method._--The substance
which is suspected to contain the poison, if solid, is reduced to a
pulp, and is mixed with sufficient water until of the consistency of
thin gruel. The urine should be evaporated to one-fourth or one-sixth
of its volume. Fæces should be well stirred up with distilled water.
The substance is then placed in a large flask together with crystals
of potassium chlorate; each 100 grammes of the substance require 3 to
4 grammes of potassium chlorate. Pure HCl of the same weight as the
original substance is then added, the flask is placed on a water-bath
and gently heated. Care must be taken that the heating is not too
brisk, as otherwise the evolution of the chlorine peroxide takes place
too rapidly. If necessary, additional crystals of potassium chlorate
are added from time to time until the fluid becomes limpid and of a
slight yellow colour, or, if there is much organic matter, until it
assumes the appearance and colour of thin oatmeal gruel. On account of
more gradual evolution of chlorine, the chlorate that is present before
the flask is heated acts much more energetically, weight for weight,
than fragments added after the liquid is heated, as a great deal of
the gas then escapes without rendering any service. If the substance
contains sugar, starch, or alcohol, extra care must be taken to avoid
frothing over. When the fluid contents are clear or reduced to a thin
consistency, the liquid is transferred to an evaporating basin, and
allowed to remain on a water-bath until the smell of chlorine has
disappeared; it is then filtered while hot. The whole of the organic
matter is not destroyed by this process, fatty substances especially
being resistant; but if the organic matter is reduced to small
fragments, any mineral poison present will be liberated.
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