Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving riskLegge, Thomas Morison, Sir
Science
Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving risk
Legge, Thomas Morison, Sir
Lead poisoning
The objections raised against this process are that some important
poisons--such, for instance, as arsenic and antimony, specially the
former--are liable to escape partially in the form of vapour, and that
others, such as lead and silver, may remain as insoluble precipitates
on the filter. As regards the first objection, it is to be observed
that, when the hydrochloric acid is diluted with water (as in a moist
method of destroying organic matter), any arsenic which may be present
in the hot solution is not given off with its acid aqueous vapour,
arsenious chloride dissolved in hydrochloric acid being volatile
only when the solvent is concentrated. Any possibility of loss may
be avoided, however, by furnishing the flask, in which the organic
matter is being destroyed, with a condenser and receiver. The second
objection, as far as lead is concerned, is met by taking care to filter
the solution whilst hot; if only a limited amount of lead is present,
it then remains in solution as chloride so long as the liquid is hot,
and will consequently pass through the filter. A considerable quantity
is kept in solution in the cold, as it forms a combination with
potassium chloride, which is more soluble than lead chloride alone. If
a large amount is present, it will not all be found in the filtrate;
the substance left on the filter, therefore, must always be tested for
lead. In toxicological work, however, the amount of lead present is not
as a rule more than will remain dissolved in the cold. Silver chloride,
being insoluble either in hot or cold water, will not pass through the
filter; consequently the salts of silver require dealing with in a
special manner.
_Dry Method._--This is effected by heating the finely divided substance
to redness, so that it is either carbonized or completely incinerated.
When cold, the residue is drenched with nitric acid, and sufficient
heat is afterwards applied to drive off the free acid. The nitrate
of the metal is then dissolved in water, filtered, and dealt with
according to the kind of metal present.
The dry method is unsuitable in the case of the more volatile metals,
as arsenic, antimony, and, in a lesser degree, lead, tin, and zinc.
Further, it is extremely difficult and troublesome to carry out with
large masses of organic matter. It is convenient with small amounts,
and in the absence of the more volatile metals yields good results.
The following two methods are given by Glaister[6] on the one hand, and
Dixon Mann[7] on the other. Both methods are good. It will be seen that
Glaister recommends the estimation of the lead as sulphide.
When minute quantities of lead are present in combination with large
amounts of organic matter, the dry process is tedious, difficult to
carry out, and uncertain in its results. The plan adopted in the
elimination of lead by Dixon Mann is as follows:
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