Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving riskLegge, Thomas Morison, Sir
Science
Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving risk
Legge, Thomas Morison, Sir
Lead poisoning
As a rule the prognosis of cases of lead poisoning occurring in
industrial conditions is more favourable when colic is a marked feature
than when it is absent, and there is no doubt that the prognosis
in cases of industrial lead poisoning at the present time is more
favourable than it was before the introduction of exhaust ventilation
and general medical supervision--a fact no doubt to be explained by the
relative decrease in the amount of lead absorbed.
REFERENCES.
[1] GOADBY, K. W.: Journ. of Hygiene, vol. ix., 1909.
[2] HUNTER, JOHN: Observations of Diseases of the Army in Jamaica.
London, 1788.
[3] DRISSOLE AND TANQUEREL: Meillère’s Le Saturnisme, p. 164.
[4] HOFFMANN: Journ. de Méd., October, 1750.
[5] WEILL AND DUPLANT: Gazette des Hôpitaux, lxxix., 796, 1902.
[6] BRIQUET: Bull. Thérap., Août, 1857.
[7] PEYROW: Thèse de Paris, 1891.
[8] STEVENS: Bulletin of Bureau of Labour, U.S.A., No. 95, p. 138,
1911.
[9] ZINN: Berl. Klin. Woch., Nr. 50, 1899.
[10] SERAFINI: Le Morgagni, No. 11, 1884.
CHAPTER XII
PREVENTIVE MEASURES AGAINST LEAD POISONING
=Amount of Lead Fume and Dust in the Atmosphere Breathed.=--Lead fuses
at 325° C. and boils at between 1450° and 1,600° C. It is volatile when
heated to a cherry-red colour--about 550° C.
Experiments[A] carried out in the laboratory of a lead smelting works
in London to determine the temperature at which leady fumes rise
from the surface of open baths of molten lead, showed that unless
pure lead is heated to about 500° C., and at the same time stirred,
no appreciable fume comes off, and that from lead, at the same
temperature, under ordinary working conditions, little or no lead
in the form of oxide passes into the air. From lead that has been
unrefined or which contains zinc--that is, lead in the earlier stages
of its manufacture (in the reverberatory furnace)--leady fume was not
given off at temperatures less than 760° C. even when stirred, because
at a temperature of 600° C. the surface of the molten metal became
covered with fluid slag, which will not allow any oxide to be given
off. Impurities such as tin or antimony prevent the oxidation of molten
lead at lower temperatures, and give it a bright, shiny colour. When
heated to about 600° C., these impurities form a slag on the surface
of the lead containing antimoniates and stannates of lead, which do
not evolve lead fumes unless heated to temperatures never likely to be
reached in open lead pots. The reason why molten refined lead can give
off lead fume more readily than those named is because the oxide formed
on the surface is a dry powder and not in the form of slag. Hence, when
the bath is stirred, some of the dry oxide is broken up and may rise
into the air. When a bath of molten lead is not stirred at all, it can
be heated to over 740° C. without finding oxide in the air aspirated--a
temperature not obtained under ordinary working conditions.
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