Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving riskLegge, Thomas Morison, Sir
Science
Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving risk
Legge, Thomas Morison, Sir
Lead poisoning
[A] In these experiments air was aspirated through an iron funnel
having an area of 113 square inches (12 inches diameter), placed at
a height of 1¹⁄₂ inches above the molten metal, and connected to an
iron tube 3 feet in length and ¹⁄₂ inch in diameter. Inside the iron
tube was a glass tube, one end reaching own to the top of the funnel
and the other connected with a tube containing pure loose asbestos
wool, and continued down to a tightly stoppered bottle holding
dilute sulphuric acid. Another glass tube connected this bottle with
an aspirator. The asbestos tube was weighed before and after each
test, and the asbestos then treated with nitric acid, and the lead
determined volumetrically. In none of the tests made was lead found
in the bottle containing sulphuric acid.
Were there nothing else to consider but escape of lead fume from a pot
or bath of molten metal, obviously hooding over of the bath and removal
of the fume from the atmosphere of the workroom would be unnecessary
until this temperature was reached. Usually, however, the bath is kept
standing exposed to the air, and the oxide which forms on the surface
has to be skimmed off periodically, and whenever the ladle is emptied
a small cloud of dust arises. Or at times, in certain processes,
chemical interaction takes place in the bath, as in the dipping of
hollow-ware articles previously cleaned in hydrochloric acid, with
evolution of fume of volatile chloride of lead. Any vessel, therefore,
of molten metallic lead in which skimming is necessary, or in which
chemical action gives rise to fume, requires a hood and exhaust
shaft, even although the temperature is little, if at all, above the
melting-point--unless, indeed, a separate exhaust can be arranged for
the removal of the dust immediately above the point where the skimmings
are deposited.
Public-domain text, read in full here on John Shaqi.
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