Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving riskLegge, Thomas Morison, Sir
Science
Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving risk
Legge, Thomas Morison, Sir
Lead poisoning
Lead ores, drosses, etc., on arrival at the factory, are, after
sampling, deposited in bins or heaps (often in the open air), and
watered to prevent dust. All ores may, and refractory ores (containing
over 4 per cent. silica) and dross must, be smelted in a blast furnace
by aid of coke. The bulk of the charge in a blast furnace may consist
of more or less complex ores of the precious metals, especially silver.
When galena is treated in a blast furnace, preliminary roasting is
indispensable, and in many smelting works its treatment takes place in
a reverberatory or open-hearth furnace, and not in a blast furnace.
The three principal methods applicable to extraction of lead from ores
are--(1) The roast and reaction method; (2) the roast and reduction
method; and (3) the precipitation process.
By the _roast and reaction method_ a part of the galena is first
converted into oxide and sulphate of lead with access of air.
Subsequently, on shutting off the air-supply and increasing the
temperature, a reaction takes place. The sulphur in the unchanged
sulphide combines with the oxygen of the oxide and sulphate to form
sulphur dioxide, which is carried away by the draught into the bricked
flue, leaving metallic lead behind. The process is carried on in a
reverberatory or open-hearth furnace.
In the _roast and reduction method_ the first portion of the process
is carried out in a reverberatory furnace, the galena being roasted
pretty completely to lead oxide and sulphate, which are then--usually
in a blast furnace--reduced to the metallic state with coke and other
reducing agents, such as iron.
By the _precipitation process_ galena was decomposed at a high
temperature by means of metallic iron, forming a mixture of iron and
lead sulphide. This method was only applicable to rich lead ores, and
is now given up.
The three methods are hardly ever independent of one another, as the
rich slag or residues, for instance, which are obtained by the first
method are retreated by the second, and the second is, as has been
stated, almost always combined with the first.
On tapping the blast or reverberatory furnace, the lead is drawn
off into a lead well or sump, from which, when cool, it is ladled
into moulds, while the slag is run into movable metal pots or along
specially-prepared channels. The slag run off from the reverberatory
furnace contains much lead locked up as silicate, which requires to be
retreated, usually in the blast furnace. During the roasting process
much raking of the material is necessary. The slag from the blast
furnace should contain less than 1 per cent. of lead.
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