Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving riskLegge, Thomas Morison, Sir
Science
Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving risk
Legge, Thomas Morison, Sir
Lead poisoning
On the Continent and in America, the Huntingdon-Heberlein process has
been extensively adopted, with lessened incidence of poisoning, the
result of mechanical methods of working, obviating hand labour, and the
low temperature (diminishing risk from lead fume) at which the roasting
is carried on. In this process the crushed ore is desulphurized by
first mixing with lime and heating in presence of air in a revolving
furnace, provided with automatic rabble, at moderate temperature (about
700° C.). Subsequently the roasted material is conveyed from closed
bins, into which it falls automatically, by dust-proof elevators to
a converter, in which atmospheric air at slight pressure is forced
through it. The agglomerated mass so formed, when tipped out of the
converter (in doing which there is risk from dust), is well damped,
broken by hand, and charged with coke in the usual way into the blast
furnace.
In some lead-smelting works the material arrives on the premises
in the form of ingots of base bullion--_i.e._, impure lead rich in
silver--the product of previous smelting of the ore where it is mined
in Australia or Spain. And one of the main objects of the blast-furnace
smelting of galena in the factory is to produce a base bullion rich
in precious metals. The lead so obtained requires further softening
or refining to get rid of copper, antimony, arsenic, and tin. This
is effected in a reverberatory furnace, first at a low temperature
to allow of formation of furnace dross, which is removed through
the working doors, and secondly with increase of heat and access of
air to oxidize, in the order named, the tin, arsenic, and antimony.
Finally the lead is tapped into kettles or pots. If free from silver,
such lead, when poured into moulds, is ready for the market; but if
rich in silver, it is treated for the recovery of that metal either
by (_a_) Pattinson’s process, depending on the higher temperature of
crystallization of lead than of an alloy of lead and silver, which
enables a separation of one from the other to be made by a process
of ladling the crystalline from the liquid portion; or, much more
commonly, by (_b_) Parkes’s process, depending on the formation,
on addition of zinc to a pot of molten lead, of crusts consisting
of an alloy of silver, lead, and zinc. The crusts obtained in the
latter process, after cooling, are broken up, placed in a crucible,
and the zinc driven off at a temperature of 1,000° C. in a dezincing
Faber du Faur retort. The rich bullion, retained either in the last
kettle by the Pattinson process, or remaining in the crucible after
dezincing, next undergoes cupellation--_i.e._, exposure to a blast
of air in a furnace. The lead is oxidized into litharge, which drops
into a receptacle below the furnace, leaving the silver behind. In all
lead-smelting works the draught from the furnace carries much dust of
ore and fuel, and fume, consisting of sulphide, sulphate, and oxides of
lead, into the flues.
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