Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
Operations at Port Pirie are conducted on a much larger scale. A
mixture of pulverized galena, powdery limestone, ironstone and sand
is fed into Ropp furnaces, of which there are five, by means of a
fluted roll placed at the base of a hopper. Each roaster deals with
100 tons of the mixture in 24 hours. About 50 per cent. of the sulphur
is eliminated from the ore by the Ropps (the galena in this case being
admixed with a large amount of blende, there being only 55 per cent.
of lead and 10 per cent. of zinc in the concentrate produced at the
Proprietary mine). The hot ore from the roasters is trucked to the
converters, there being 17 of these ranged in line. The converters here
are large segmental cast-iron pots hung on trunnions; each is about 8
ft. diameter and 6 ft. deep, and holds an 8-ton charge. At about two
feet from the bottom an annular perforated plate fits horizontally;
a shallow frustrum of a cone, also perforated, rests on this; while
a plate with a few perforations closes the top of the frustrum. The
whole serves as a wind-box. A conical hood with flanged edges rests
on the flanged edges of the converter, giving a close joint. This
hood is provided with doors which allow the charge to be barred if
necessary. A pipe about 1 ft. 9 in. diameter, fitted with a telescopic
sliding arrangement, allows for the raising or lowering of the hood by
block and tackle, and thus enables the converter to be tilted up and
its products emptied. The cast-iron pots stand very well; they crack
sometimes, but they can be patched up with an iron strap and rivets.
Only two pots have been lost in 18 months.
Air enters at a pressure of about 24 oz. and the time taken for
conversion is about four hours. The sulphur contents are reduced to
about three per cent. It is found that the top of the charge is not so
well converted as the interior. There is practically no loss of lead
or silver due to volatilization and very little due to escape of zinc.
It has also been found that practically all the limestone fed into
the Ropp is converted into calcium sulphate; also that a considerable
portion of lead becomes sulphate, and it is considered that lead
sulphate is as necessary for the process as galena.
The value of the process may be judged from the fact that better work
is now done with 8 blast furnaces than was done with 13 before the
process was adopted. In addition to the sintered product from the
Huntington-Heberlein pots, sintered slime, obtained by heap roasting,
and flux consisting of limestone and ironstone, are fed into the
furnaces, which take 2000 long tons per day of ore, fluxes and fuel.
The slags now being produced average: SiO₂, 25 to 26 per cent.; FeO,
1 to 3 per cent.; MnO, 5 to 5.5; CaO, 15.5 to 17; ZnO, 13; Al₂O₃,
6.5; S, 3 to 4; Pb, by wet assay, 1.2 to 1.5 per cent.; and Ag, 0.7 oz.
per ton. Although this comparatively large quantity of sulphur remains,
yet no matte is formed.
Public-domain text, read in full here on John Shaqi.
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