Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
In the old process the slag formed in the furnace flows out
continuously through the tap-hole into iron pots placed in front of
the spout. A number of such pots are so arranged on a revolving table
that as soon as one is filled the next empty can be brought up to the
duct; thus the slag first poured in has time to cease fuming and to
solidify before it is removed. The vapors arising from the slag as it
flows out are conveyed away through hoods. At the same time with the
slag, lead matte also issues from the furnace. Now the greater the
quantity of lead matte, the more smoke is also produced; and, with
the comparatively high proportion of lead matte resulting from the
old process, the quantity of smoke was so great that the ventilation
appliances were no longer sufficient to cope with it, thus allowing
vapors to escape into the work-room.
The work-lead collects at the back of the furnace in a well, from which
it is from time to time ladled into molds placed near by. If the lead
is allowed to cool sufficiently in the well, it does not fume much in
the ladling out. But when the furnace runs very hot (which sometimes
happens), the lead also is hotter and is more inclined to volatilize.
In this event the danger of lead-poisoning is very great, for the
workman has to stand near the lead sump.
A still greater danger attends the work of barring down and cleaning
out the furnace. The barring down serves the purpose of loosening
the charge in the zone of fusion; at the same time it removes any
crusts formed on the sides of the furnace, or obstructions stopping
up the tuyeres. With the old furnaces, and their strong tendency to
crust, this work had to be undertaken almost every day, the men being
compelled to work for rather a long time and often very laboriously
with the heavy iron tools in the immediate neighborhood of the glowing
charge, the front of the furnace being torn open for this purpose. In
this operation they were exposed without protection to the metallic
vapors issuing from the furnace, inasmuch as the ventilating appliances
had to be partially removed during this time, in order to render it at
all possible to do the work.
In a similar manner, but only at the time of shutting down a shaft
furnace, the cleaning out (that is to say, the withdrawing of no
longer fused but still red-hot portions of the charge left in the
furnace) is carried out. In this process, however, the glowing material
brought out could be quenched with cold water to such a point that the
evolution of metallic vapors could be largely avoided.
Lastly, the mode of charging of the shaft furnace is also to be
regarded as a cause of poisoning, inasmuch as it is impossible to
avoid entirely the raising of dust in the repeated act of dumping and
turning over the materials for smelting, in preparing the mix, and in
subsequently charging the furnace.
Public-domain text, read in full here on John Shaqi.
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