Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
That the roaster gases from the reverberatory-smelting and sintering
furnaces did not show such a high percentage of sulphur dioxide must
be ascribed chiefly to the circumstance that the roasting was much
slower, and that the gases were largely diluted with air already at the
point where they are formed, as the work must always be done with the
working-doors open. In the Huntington-Heberlein process, on the other
hand, the aim is to prevent, as far as possible, the access of air from
outside while blowing the charge. The more perfectly this is effected,
and the greater the quantity of ore to be blown in the converters, the
higher will also be the percentage of sulphur dioxide in the waste
gases. This circumstance has not only furnished the inducement, but it
has rendered it possible to approach the plan of utilizing the sulphur
dioxide for the manufacture of sulphuric acid. If this should be done
successfully (which, according to the experiments carried out, there
is reasonable ground to expect), the present disadvantage might be
turned into an advantage. This has the more significance because an
essential constituent of the lead ore—the sulphur—will then no longer,
as hitherto, have to be regarded as wholly lost.[31]
THE HUNTINGTON-HEBERLEIN PROCESS
BY THOMAS HUNTINGTON AND FERDINAND HEBERLEIN
(May 26, 1906)
This process for roasting lead sulphide ores has now fairly
established itself in all parts of the world, and is recognized by
metallurgical engineers as a successful new departure in the method of
desulphurization. It offers the great advantage over previous methods
of being a more scientific application of the roasting reactions (of
the old well-used formulæ PbS + 3O = PbO + SO₂ and PbS + PbSO₄
+ 2O = 2PbO + 2SO₂) and admits of larger quantities being handled
at a time, so that the use of fuel and labor are in proportion to the
results achieved, and also there is less waste all around in so far
as the factors necessary for the operation—fuel, labor and air—can
be more economically used. The workman’s time and strength are not
employed in laboriously shifting the ore from one part of the furnace
to another with a maximum amount of exertion and a minimum amount of
oxidation. The fuel consumed acts more directly upon the ore during the
first part of the process in the furnace and its place is taken by the
sulphur itself during the final and blowing stage, so that during the
whole series of operations more concentrated gases are produced and
consequently the large excess of heated air of the old processes is
avoided to such an extent that the gases can be used for the production
of sulphuric acid.
Public-domain text, read in full here on John Shaqi.
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