Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
With a modern well-constructed plant practically all the evils of
the old hand-roasting furnaces are avoided, and besides the notable
economy achieved by the H.-H. process itself, the health and well-being
of the workmen employed are greatly advanced, so that where hygienic
statistics are kept it is proved that lead-poisoning has greatly
diminished. It is only natural, therefore, that the H.-H. process
should have been a success from the start, popular alike with managers
and workmen once the difficulties inseparable from the introduction of
any new process were overcome.
Simple as the process now appears, however, it is the result of many
years of study and experiment, not devoid of disappointments and at
times appearing to present a problem incapable of solution. The first
trials were made in the smelting works at Pertusola, Italy, as far
back as 1889, where considerable sums were devoted every year to this
experimental work and lead ore roasting was almost continuously on the
list of new work from 1875 on.
It may be interesting to mention that at this time the Montevecchio
ores (containing about 70 per cent. lead and about 15 per cent.
sulphur, together with a certain amount of zinc and iron) were
considered highly refractory to roast, and the only ores approved of
by the management of the works at this date were the Monteponi and
San Giovanni first-class ores (containing about 80 per cent. lead),
and the second-class carbonates (with at least 60 per cent. lead and
5 per cent. sulphur). It must be noted that a modified Flintshire
reverberatory process was in use in the works, which could deal
satisfactorily only with this class of ore, so that, as these easy ores
diminished in quantity every year and their place was taken by the
“refractory” Montevecchio type, the roasting problem was always well to
the front at the Pertusola works.
It may be asserted that almost every known method of desulphurization
was examined and experimented upon on a large scale. Gas firing was
exclusively used on certain classes of ores for several years with
considerable success, and revolving furnaces of the Brückner type—gas
fired—were also tried. Although varying degrees of success were
obtained, no really great progress was made in actual desulphurization;
methods were cheapened and larger quantities handled at a time, but
the final product—whether sintered or in a pulverulent state—seldom
averaged much under 5 per cent. sulphur, while the days of the
old “gray slags” (1 per cent. to 2 per cent. sulphur) from the
reverberatories totally disappeared, together with the class of ores
which produced them.
During the long period of these experiments in desulphurization various
facts were established:
Public-domain text, read in full here on John Shaqi.
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