Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
(1) That sulphide of lead—especially in a pulverulent state—could not
be desulphurized in the same way as other sulphides, such as sulphides
of iron, copper, zinc, etc., because if roasted in a mechanical
furnace the temperature had to be kept low enough to avoid premature
sintering, which would choke the stirrers and cause trouble by the
ore clogging on the sides and bottom of the furnace. If, however, the
ore was roasted in a “dry state” at low temperature, a great deal of
sulphur remained in the product as sulphate of lead, which was as
bad for the subsequent blast-furnace work as the sulphide of lead
itself. When air was pressed through molten galena—in the same way as
through molten copper matte—a very heavy volatilization of lead took
place, while portions of it were reduced to metal or were contained as
sulphide in the molten matte, so that a good product was not obtained.
(2) That no complete dead roast of lead ores could be obtained unless
the final product was thoroughly smelted and agglomerated.
(3) That a well roasted lead ore could be obtained by oxidizing the PbS
with compressed air, after the ore had been suitably prepared.
(4) That metal losses were mainly due to the excessive heat produced in
the oxidation of PbS to PbO, and other sulphides present in the ore.
It was by making use of these facts that the H.-H. roasting process
was finally evolved, and by carefully applying its principles it is
possible to desulphurize completely the ore to a practically dead roast
of under 1 per cent. sulphur; in practice, however, such perfection
is unnecessary and a well agglomerated product with from 2 to 2.5 per
cent. sulphur is all that is required. During some trials in Australia,
where a great degree of perfection was aimed at, a block of over 2000
tons of agglomerated, roasted ore was produced containing 1 per cent.
sulphur (as sulphide); as the ores contained an average of about 10 per
cent. Zn, this was a very fine result from a desulphurization point
of view, but it was not found that this 1 per cent. product gave any
better results in the subsequent smelting in the blast furnace than
later on a less carefully prepared material containing 2.5 per cent.
sulphur.
Public-domain text, read in full here on John Shaqi.
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