Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
The ore on leaving the furnace is charged into the converters by
various mechanical means (Jacob’s ladders, conveyors, etc.). The
converter charge usually consists of some hot ore direct from the
furnace, on top of which ore is placed which has been cooled down by
storage in bins or by the addition of water. The converter is generally
filled in two charges of five tons each, and the blowing time should
not be more than 4 to 6 hours. The product obtained should be porous
and well agglomerated, but easily broken up, tough melted material
being due to an excess of silica and too much lead sulphide. Attention,
therefore, to these two points (good preliminary roasting and
correction of the charge by lime) obviates this trouble. This roasted
ore should not contain more than about 1.5 to 2 per cent. sulphur,
and in a modern blast furnace gives surprisingly good results, the
matte-fall being in most cases reduced to nothing, and the capacity of
the furnace is largely increased, while the slags are poorer.
If the converter charge has been properly prepared, the blowing
operation proceeds with the greatest smoothness and requires very
little attention on the part of the workmen, the heat and oxidation
rise gradually from the bottom and volatilization losses remain low, so
that it is possible, if desired, to produce hot concentrated sulphurous
gases suitable for the manufacture of sulphuric acid.
Besides the actual economy obtained in roasting ores by the process,
a great feature of its success has been the remarkable improvement
in smelting and reducing the roasted ore as compared with previous
experience. This is due to the nature of the roasted material, which,
besides being much poorer in sulphur than was formerly the case, is
thoroughly porous and well agglomerated and contains—if the original
mixture is properly made—all the necessary slagging materials itself,
so that it practically becomes a case of smelting slags instead of ore,
and to an expert the difference is evident.
Experience has shown that on an average the improvement in the capacity
of the blast furnace may be taken at about 50 to 100 per cent., so that
in works using the H.-H. process—after its complete introduction—about
half the blast furnaces formerly necessary for the same tonnage were
blown out. The matte-fall has become a thing of the past, so that,
except in those cases where some matte is required to collect the
copper contained in the ores, lead matte has disappeared and the
quantity of flue dust as well as the lead and silver losses have been
greatly reduced.
Public-domain text, read in full here on John Shaqi.
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