Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
In certain exceptional cases and with ores poor in sulphur, direct
blowing might be applicable, but for the general run of lead ores no
economy can be expected by doing away with the preliminary roast.
MAKING SULPHURIC ACID AT BROKEN HILL
(August 11, 1904)
The Broken Hill Proprietary Company has entered upon the
manufacture of sulphuric acid on a commercial scale. The acid is
practically a by-product, being made from the gases emanating
from the desulphurization of the ores, concentrates, etc., by the
Carmichael-Bradford process. The acid can be made at a minimum of
cost, and thus materially enhances the value of the process recently
introduced for the separation of zinc blende from the tailings by
flotation. The following particulars are taken from a recently
published description of the process: The ores, concentrates, slimes,
etc., as the case may be, are mixed with gypsum, the quantity of the
latter varying from 15 to 25 per cent. The mixture is then granulated
to the size of marbles and dumped into a converter. The bottom of
the charge is heated from 400 to 500 deg. C. It is then subjected to
an induced current of air, and the auxiliary heat is turned off. The
desulphurization proceeds very rapidly with the evolution of heat and
the gases containing sulphurous anhydride. The desulphurization is very
thorough, and no losses occur through volatilization. The sulphur thus
rendered available for acid making is rather more than is contained in
the ore, the sulphur in the agglomerated product being somewhat less
than that accounted for by the sulphur contained in the added gypsum.
Thus from one ton of 14 per cent. sulphide ore it is possible to make
about 12 cwt. of chamber acid, fully equaling 7 cwt. of strong acid.
The plant at present in use, which comprises a lead chamber of 40,000
cu. ft., can turn out 35 tons of chamber acid per week. This plant is
being duplicated, and it has also been decided to erect a large plant
at Port Pirie for use in the manufacture of superphosphates. It is
claimed that the production of sulphuric acid from ores containing only
14 per cent. of sulphur establishes a new record.
THE CARMICHAEL-BRADFORD PROCESS
BY DONALD CLARK
(November 3, 1904)
Public-domain text, read in full here on John Shaqi.
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