Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
“The particles of limestone act mechanically by separating the
particles of lead ore from each other in such a way that premature
agglomeration is prevented and the whole mass is loosened and rendered
accessible to air; and, moreover, the limestone moderates the high
reaction temperature resulting from the burning of the sulphur, so
that the liquefaction of the galena, the sublimation of lead sulphide,
and the separation of metallic lead are avoided. The moderation of
the temperature of reaction is caused by the decomposition of the
limestone into caustic lime and carbon dioxide, whereby a large amount
of heat becomes latent. Further, the decomposition of the limestone
causes chemical reactions, lime being formed, which at the moment of
its formation is partly converted into sulphate of lime at the expense
of the sulphur contained in the ore, and this sulphate of lime, when
the scorification takes place, is transformed into calcium silicate
by the silicic acid, the sulphuric acid produced thereby escaping.
The limestone also largely contributes to the desulphurization of the
ore, as it causes the production of sulphuric acid at the expense of
the sulphur of the ore, which sulphuric acid is a powerful oxidizing
agent. If, therefore, a mixture of raw lead ore and limestone (which
mixture must, of course, contain a sufficient amount of silicic acid
for forming silicates) be introduced into a chamber and a current of
air be blown through the mixture, and at the same time the part of the
mixture which is near the blast inlet be ignited, the combustion of the
sulphur will give rise to very energetic reactions, and sulphurous
acid, sulphuric acid, lead oxide, sulphates and silicates are produced.
The sulphurous acid and the carbon dioxide escape, while the sulphuric
acid and sulphates act in their turn as oxidizing agents on the
undecomposed galena. Part of the sulphates is decomposed by the silicic
acid, thereby liberating sulphuric acid, which, as already stated, acts
as an oxidizing agent. The remaining lead oxide combines finally with
the gangue of the ore and the non-volatile constituents of the flux
(the limestone) to form the required slag. These several reactions
commence at the blast inlet at the bottom of the chamber, and extend
gradually toward the upper portion of the charge of ore and limestone.
Liquefaction of the ores does not take place, for although a slag is
formed it is at once solidified by the blowing in of the air, the
passages formed thereby in the hardening slag allowing of the continued
passage therethrough of the air. The final product is a silicate
consisting of lead oxide, lime, silicic acid, and other constituents of
the ore, which now contains but little or no sulphur and constitutes a
coherent solid mass, which, when broken into pieces, forms a material
suitable to be smelted.
Public-domain text, read in full here on John Shaqi.
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