Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
“The quantity of limestone required for the treatment of the lead
ores varies according to the constitution of the ores. It should,
however, amount generally to from 15 to 20 per cent. As lead ores do
not contain the necessary amount of limestone as a natural constituent,
a considerable amount of limestone must be added to them, and this
addition may be made either during the dressing of the ores or
subsequently.
“For the satisfactory working of the process, the following precautions
are to be observed: In order that the blowing in of the air may not
cause particles of limestone to escape in the form of dust before
the reaction begins, it is necessary to add to the charge before it
is subjected to the action in the chamber a considerable amount of
water—say 5 per cent. or more. This water prevents the escape of dust,
and it also contributes considerably to the formation of sulphuric
acid, which, by its oxidizing action, promotes the reaction, and,
consequently, also the desulphurization. It is advisable, in conducting
the operation, not to fill the chamber with the charge at once, but
first only partly to fill it and add to the charge gradually while the
chamber is at work, as by this means the reaction will take place more
smoothly in the mass.
[Illustration: Fig. 19.—Charge Dumped.]
“It is advantageous to proceed as follows: The bottom part of a
chamber of any suitable form is provided with a grate, on which is
laid and ignited a mixture of fuel (coal, coke, or the like) and
pieces of limestone. By mixing the fuel with pieces of limestone the
heating power of the fuel is reduced and the grate is protected,
while at the same time premature melting of the lower part of the
charge is prevented; or the grate may be first covered with a layer
of limestone and the fuel be laid thereon, and then another layer of
limestone be placed on the fuel. On the material thus placed in the
chamber, a uniform charge of lead ore and limestone—say about 12 in.
high—is placed, this having been moistened as previously explained.
Under the influence of the air-blast and the heat, the reactions
hereinbefore described take place. When the upper surface of the first
layer becomes red-hot, a further charge is laid thereon, and further
charges are gradually introduced as the surface of the preceding
charge becomes red-hot, until the chamber is full. So long as charges
are still introduced a blast of air of but low pressure is blown
through; but when the chamber is filled a larger quantity of air at a
higher pressure is blown through. The scorification process then takes
place, a very powerful desulphurization having preceded it. During the
scorification the desulphurization is completed.
“When the process is completed, the chamber is tilted and the
desulphurized mass falls out and is broken into small pieces for
smelting.”
Public-domain text, read in full here on John Shaqi.
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