Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
It may now be attempted to summarize the cost of the converting
process. Assuming the case of an ore assaying lead, 50 per cent.; iron,
15; sulphur, 22; silica, 8, and alumina, etc., 5, let it be supposed
that it is to be fluxed with pure limestone and pure quartz, with the
aim to make a slag containing silica, 30; ferrous oxide, 40; and lime,
20 per cent. A ton of ore will make, in round numbers, 1000 lb. of
slag, and will require 344 lb. of limestone and 130 lb. of quartz,
or we may say roughly one ton of flux must be added to four tons of
ore, wherefore the ore will constitute 80 per cent. of the charge. In
reducing the charge to 3 per cent. sulphur it will lose ultimately
through expulsion of sulphur and carbon dioxide (of the limestone)
about 20 per cent. in weight, wherefore the quantity of material to
be smelted in the blast furnace will be practically equivalent to
the raw sulphide ore in the charge for the roasting furnaces; but in
the roasting furnace the charge is likely to gain weight, because of
the formation of sulphates. Taking the charge, which I have assumed
above, and reckoning that as it comes from the roasting furnace it
will contain 10 per cent. sulphur, all in the form of sulphate, either
of lead or of lime, and that the iron be entirely converted to ferric
oxide, in spite of the expulsion of the carbon dioxide of the limestone
and the combustion of a portion of the sulphur of the ore as sulphur
dioxide, the charge will gain in weight in the ratio of 1:1.19. This,
however, is too high, inasmuch as a portion of the sulphur will remain
as sulphide while a portion of the iron may be as ferrous oxide. The
actual gain in weight will consequently be probably not more than
one-tenth. The following theoretical calculation will illustrate the
changes:
─────────────────────┬──────────────────────┬─────────────────────────
RAW CHARGE │ SEMI-ROASTED CHARGE │ FINISHED CHARGE
─────────────────────┼──────────────────────┼─────────────────────────
{1000 lb. Pb │ {1154 lb. PbO │ { 1154 lb. PbO
{ 300 lb. Fe │ { 428 lb. Fe₂O₃ │ { 428 lb. Fe₂O₃(?)
Ore { 160 lb. SiO₂ │ Ore { 160 lb. SiO₂ │ Ore { 160 lb. SiO₂
{ 100 lb. Al₂O₃,│ { 100 lb. Al₂O₃, │ { 100 lb. Al₂O₃,
etc. │ etc. │ etc.
{ 440 lb. S │ { 300 lb. S │ { 68 lb. S
│ │
{ 130 lb. SiO₂ │ { 130 lb. SiO₂ │ { 130 lb. SiO₂
Flux { 344 lb. CaCO₃ │ Flux { 193 lb. CaO │ Flux { 193 lb. CaO
│ 450 lb. O │
———— │ ———— │ ————
2474 lb. │ 2915 lb. │ 2233 lb.
│ │
│ 10% S. │ 3% S.
─────────────────────┴──────────────────────┴─────────────────────────
Ratios:
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