Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
If much copper is present the
dross may contain more gold and silver than the retort bullion itself.
In this connection I remember an occasion on which some retort dross
yielded gold and silver to the extent of over 800 and 3000 oz. per ton
respectively.
_Cupellation._—Retort bullion is first concentrated (together with
bullion resulting from dross treatment) to 50 to 60 per cent. gold and
silver in a water-jacketed cupel. The side lining is protected by an
inch water-pipe imbedded in the lining at the litharge level or by a
water-jacket, the inner face of which is of copper; the cupel has also
a water-jacketed breast so that the front is not cut down. The cupel
lining may be composed of limestone, cement, fire-clay and magnesite
in various proportions, but a simple lining of sand and cement was
found quite satisfactory. When the bullion is concentrated up to 50 to
60 per cent. gold and silver, it is baled out and transferred to the
finishing cupel, where it is run up to about 0.995 fine; it is then
ready either for the melting-pot or parting plant. The refining test,
by the way, is not water-cooled.
Re-melting is done in 200-oz. plumbago crucibles and presents no
special features. In the case of doré bullion low in gold, “sprouting”
of the silver is guarded against by placing a piece of wood or charcoal
on the surface of the metal before pouring, and any slag is kept back.
The quantity of slag formed is, of course, very small, so that the bars
do not require much cleaning.
The parting plant was not in operation in my time, and I am therefore
unable to go into details. The process arranged for was briefly as
follows: Solution of the doré bullion in H₂SO₄; crystallization
of silver as monosulphate by dilution and cooling; decomposition of
silver sulphate by ferrous sulphate solution giving metallic silver and
ferric sulphate, which is reduced to the ferrous salt by contact with
scrap iron. The gold and silver are washed thoroughly with hot water
and cast into bars.
In conclusion, some variations in practice may be noted. The use of
two furnaces in the softening process has already been mentioned; by
this means the drossing and softening are more perfect and subsequent
operations thereby facilitated; further, the furnaces, being kept at
a more equable temperature, are less subject to wear and tear. Zinc
crusts are sometimes skimmed direct into an alloy press in which
the excess of lead is squeezed out while still molten; liquation is
then unnecessary. Refining of the lead may be effected by a simple
scorification in a reverberatory, the soft lead being run into a kettle
from which it is molded into market bars.
THE ELECTROLYTIC REFINING OF BASE LEAD BULLION
BY TITUS ULKE
(October 11, 1902)
Public-domain text, read in full here on John Shaqi.
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