Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
_Treatment of Zinc Crusts._—Having disposed of the lead, let us
return now to the zinc crusts. These are first liquated in a small
reverberatory furnace, the hearth of which is formed of a cast-iron
plate (the edges of the long sides being turned up some 4 in.) laid on
brasque filling, with a fall from bridge to flue of ¾ in. per foot and
also sloping from sides to center. The operation is conducted at a low
temperature and the charge is turned over at intervals, the liquated
lead running out into a small separately fired kettle. This lead rarely
contains more than a few ounces of silver per ton; it is baled into
bars, and returned to the zinking kettles or worked up in a separate
charge. In two to three hours the crust is as “dry” as it is advisable
to make it, and the liquated alloy is raked out over a slanting
perforated plate to break it up and goes to the retort bin.
_Retorting the Alloy._—This is carried on in Faber du Faur tilting
furnaces—simply a cast-iron box swinging on trunnions and lined with
firebrick. Battersea retorts (class 409) holding 560 lb. each are
used; their average life is about 30 charges. The retorts are charged
hot, a small shovel of coal being added with the alloy. The condenser
is now put in place and luted on; it is made of ⅛ in. iron bent to
form a cylinder 12 in. in diameter, open at one end; it is lined with
a mixture of lime, clay and cement. It has three holes, one on the
upper side close to the furnace and through which a rod can be passed
into the retort, a vent-hole on the upper side away from the furnace,
and a tap-hole on the bottom for condensed zinc. In an hour or so the
flame from the vent-hole should be green, showing that distillation has
begun. When condensation ceases (shown by the flame) the condenser is
removed and the bullion skimmed and poured into bars for the cupel. The
products of retorting are bullion, zinc, zinc powder and dross. Bullion
goes to the cupel, zinc is used again in the desilverizing kettles,
powder is sieved to take out scraps of zinc and returned to the blast
furnace, or it may be, and sometimes is, used as a precipitating
agent in cyanide works; dross is either sweated down in a cupel with
lead and litharge, together with outside material such as zinc gold
slimes from cyanide works, jeweler’s sweep, mint sweep, etc., or in
the softening furnace after the antimony has been taken off. In either
case the resulting slag goes back to the blast furnace. The total
weight of alloy treated is approximately 7 per cent. of the original
base bullion. The zinc recovered is about 60 per cent. of that used
in desilverizing. The most important source of temporary loss is the
retort dross (consisting of lead-zinc-copper alloy with carbon, silica
and other impurities), and it is here that the necessity of removing
copper in the softening process is seen, since any copper comes out
with the zinc crusts and goes on to the retorts, where it enters the
dross, carrying gold and silver with it.
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