Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
The cathode sheets which receive the regular lead deposits are thin
lead plates obtained by electrodeposition upon and stripping from
special cathodes of sheet steel. The latter are prepared for use by
cleaning, flashing with copper, lightly lead-plating in the tanks, and
greasing with a benzine solution of paraffin, dried on, from which the
deposited lead is easily stripped.
The anodes and cathodes are separated by a space of 1½ to 2 in. in the
tank and are electrically connected in multiple, the tanks being in
series circuit. The fall in potential between tanks is only about 0.2
of a volt, which remarkably low voltage is due to the high conducting
power of the electrolyte and to some extent to the system of contacts
used. These contacts are small wells of mercury in the bus-bars, large
enough to accommodate copper pins soldered to the iron cathodes or
clamped to the anodes. Only a small amount of mercury is required.
Current strengths of from 10 to 25 amperes per sq. ft. have been used,
but at Trail 14 amperes have given the most satisfactory results as
regards economy of working and the physical and chemical properties of
the refined metal produced.
A current of 1 ampere deposits 3.88 grams of lead per hour, or
transports 3¼ times as much lead, in this case, as copper with an
ordinary copper-refining solution. A little over 1000 kg., or 2240
lb., requires about 260,000 ampere hours. At 10 amperes per sq. ft. the
cathode (or anode) area should be about 1080 sq. ft. per ton of daily
output. Taking a layer of electrolyte 1.5 in. thick, 135 cu. ft. will
be found to be the amount between the electrodes, and 175 cu. ft. may
be taken as the total quantity of solution necessary, according to Mr.
Betts’ estimate. The inventor states that he has worked continuously
and successfully with a drop of potential of only 0.175 volt per tank,
and that therefore 0.25 volt should be an ample allowance in regular
refining. Quoting Mr. Betts; “260,000 ampere hours at 0.25 volt works
out to 87 electrical h.p. hours of 100 h.p. hours at the engine shaft,
in round numbers. Estimating that 1 h.p. hour requires the burning of
1.5 lb. of coal, and allowing say 60 lb. for casting the anodes and
refined lead, each ton of lead refined requires the burning of 210 lb.
of fuel.” With coal at $6 per ton the total amount of fuel consumed,
therefore, should not cost over 60c., which is far below the cost of
fire-refining base lead bullion, as we know.
Public-domain text, read in full here on John Shaqi.
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