Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
In the Betts electrolytic process, practically all the impurities
in the base bullion remain as a more or less adherent coating on
the anode, and only the zinc, iron, cobalt and nickel present go
into solution. The anode residue consists practically of all the
copper, antimony, bismuth, arsenic, silver and gold contained in the
bullion, and very nearly 10 per cent. of its weight in lead. Having
the analysis of any bullion, it is easy to calculate with these data
the composition of the anode residue and the rate of pollution of the
electrolyte. Allowing 175 cu. ft. of electrolyte per ton of daily
output, it will be found that in the course of a year these impurities
will have accumulated to the extent of a very few per cent. Estimating
that the electrolyte will have to be purified once a year, the amount
to be purified daily is less than 1 cu. ft. for each ton of output.
The amount of lead not immediately recovered in pure form is about
0.3 per cent., most of which is finally recovered. As compared with
the ordinary fire-refined lead, the electrolytically refined lead is
much purer and contains only mere traces of bismuth, when bismuthy
base bullion is treated. Furthermore, the present loss of silver in
fire refining, amounting, it is claimed, to about 1½ per cent. of the
silver present, and covered by the ordinary loss in assay, is to a
large extent avoided, as the silver in the electrolytic process is
concentrated in the anode residue with a very small loss, and the loss
of silver in refining the slimes is much less than in treating the
zinc crusts and refining the silver residue after distillation. The
silver slimes obtained at Trail, averaging about 8000 oz. of gold and
silver per ton, are now treated at the Seattle Smelting and Refining
Works. There the slimes are boiled with concentrated sulphuric acid and
steam, allowing free access of air, which removes the greater part of
the copper. The washed residue is then dried in pans over steam coils,
and melted down in a magnesia brick-lined reverberatory, provided
with blast tuyeres, and refined. In this reverberatory furnace the
remainder of the copper left in the slimes after boiling is removed by
the addition of niter as a flux, and the antimony with soda. The doré
bars finally obtained are parted in the usual way with sulphuric acid,
making silver 0.999 fine and gold bars at least 0.992 fine.
Mr. Betts treated 2000 grams of bullion, analyzing 98.76 per cent. Pb,
0.50 Ag, 0.31 Cu, and 0.43 Sb with a current of 25 amp. per square
foot in an experimental way, and obtained products of the following
composition:
Refined Lead: 99.9971 per cent. Pb, 0.0003 Ag, 0.0007 Cu, and 0.0019 Sb.
Anode Residue: 9.0 per cent. Pb, 36.4 Ag, 25.1 Cu, and 2.95 Sb.
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