Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
My first experiments were carried out without the addition of gelatine
to the fluosilicate solution. The lead deposit consisted of more or
less separate crystals that grew toward the anode, and, finally, caused
short circuits. The cathodes, which were sheet-iron plates, lead-plated
and paraffined, had to be removed periodically from the tanks and
passed through rolls, to pack down the lead. When gelatine has been
added in small quantities, the density of the lead is greater than can
be produced by rolling the crystalline deposit, unless great pressure
is used.
The Canadian Smelting Works, Trail, B. C. , have installed a refinery,
making use of this process. There are 28 refining-tanks, each 86 in.
long, 30 in. wide and 42 in. deep, and each receiving 22 anodes of
lead bullion with an area of 26 by 33 in. exposed to the electrolyte
on each side, and 23 cathodes of sheet lead, about 1/16 in. thick,
prepared by deposition on lead-plated and paraffined iron cathodes. The
cathodes are suspended from 0.5 by 1 in. copper bars, resting crosswise
on the sides of the tanks. The experiment has been thoroughly tried of
using iron sheets to receive a deposit thicker than 1/16 in.; that is,
suitable for direct melting without the necessity of increasing its
weight by further deposition as an independent cathode; but the iron
sheets are expensive, and are slowly pitted by the action of the acid
solution; and the lead deposits thus obtained are much less smooth and
pure than those on lead sheets.
The smoothness and the purity of the deposited lead are proportional.
Most of the impurity seems to be introduced mechanically through the
attachment of floating particles of slime to irregularities on the
cathodes. The effect of roughness is cumulative; it is often observed
that particles of slime attract an undue amount of current, resulting
in the lumps seen in the cathodes. Samples taken at the same time
showed from 1 to 2.5 oz. silver per ton in rough pieces from the iron
cathodes, 0.25 oz. as an average for the lead-sheet cathodes, and only
0.04 oz. in samples selected for their smoothness. The variation in
the amount of silver (which is determined frequently) in the samples
of refined lead is attributed not to the greater or less turbidity of
the electrolyte at different times, but to the employment of new men in
the refinery, who require some experience before they remove cathodes
without detaching some slime from the neighboring anodes.
Public-domain text, read in full here on John Shaqi.
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