Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
Each tank is capable of yielding, with a current of 4000 amperes,
750 lb. of refined lead per day. The voltage required to pass this
current was higher than expected, as explained below; and for this
reason, and also because the losses of solution were very heavy until
proper apparatus was put in to wash thoroughly the large volume of
slime produced (resulting in a weakened electrolyte), the current used
has probably averaged about 3000 amperes. The short circuits were
also troublesome, though this difficulty has been greatly reduced by
frequent inspection and careful placing of the electrodes. At one time,
the solution in use had the following composition in grams per 100
c.c.: Pb, 6.07; Sb, 0.0192; Fe, 0.2490; SiF₆, 6.93, and As, a trace.
The current passing was 2800 amperes, with an average of about 0.44
volts per tank, including bus-bars and contacts. It is not known what
was the loss of efficiency on that date, due to short circuits; and
it is, therefore, impossible to say what resistance this electrolyte
constituted.
Hydrofluoric acid of 35 per cent., used as a starting material for the
preparation of the electrolyte, is run by gravity through a series of
tanks for conversion into lead fluosilicate. In the top tank is a layer
of quartz 2 ft. thick, in passing through which the hydrofluoric acid
dissolves silica, forming fluosilicic acid. White lead (lead carbonate)
in the required quantity is added in the next tank, where it dissolves
readily and completely with effervescence. All sulphuric acid and any
hydrofluoric acid that may not have reacted with silica settle out
in combination with lead as lead sulphate and lead fluoride. Lead
fluosilicate is one of the most soluble of salts; so there is never
any danger of its crystallizing out at any degree of concentration
possible under this method. The lead solution is then filtered and run
by gravity into the refining-tanks.
The solution originally used at Trail contained about 6 per cent. Pb
and 15 per cent. SiF₆.
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