Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
The electrolyte takes up no impurities, except, possibly, a small part
of the iron and zinc. Estimating that the anodes contain 0.01 per
cent. of zinc and soluble iron, and that there are 150 cu. ft. of the
solution in the refinery for every ton of lead turned out daily, in
one year the 150 cu. ft. will have taken up 93 lb. of iron and zinc,
or about 1 per cent. These impurities can accumulate to a much greater
extent than this before their presence will become objectionable. It
is possible to purify the electrolyte in several ways. For example,
the lead can be removed by precipitation with sulphuric acid, and
the fluosilicic acid precipitated with salt as sodium fluosilicate.
By distillation with sulphuric acid the fluosilicic acid could be
recovered, this process, theoretically, requiring but one-third as much
sulphuric acid as the decomposition of fluorspar, in which the fluorine
was originally contained.
The only danger of lead-poisoning to which the workmen are exposed
occurs in melting the lead and casting it. In this respect the
electrolytic process presents a distinct sanitary advance.
For the treatment of slime, the only method in general use consists in
suspending the slime in a solution capable of dissolving the impurities
and supplying, by a jet of steam and air forced into the solution, the
air necessary for its reaction with, and solution of, such an inactive
metal as copper. After the impurities have been mostly dissolved, the
slime is filtered off, dried and melted, under such fluxes as soda, to
a doré bullion.
The amount of power required is calculated thus: Five amperes in 24
hours make 1 lb. of lead per tank. One ton of lead equals 10,000
ampere-days, and at 0.35 volts per tank, 3500 watt-days, or 4.7
electric h.p. days. Allowing 10 per cent. loss of efficiency in the
tanks (we always get less lead than the current which is passing would
indicate), and of 8 per cent. loss in the generator, increases this to
about 5.6 h.p. days, and a further allowance for the electric lights
and other applications gives from 7 to 8 h.p. days as about the amount
per ton of lead. At $30 per year, this item of cost is something like
65c. per ton of lead. So this is an electro-chemical process not
especially favored by water-power.
The cost of labor is not greater than in the zinc-desilverization
process. A comparison between this process and the Parkes process, on
the assumption that the costs for labor, interest and general expenses
are about equal, shows that about $1 worth of zinc and a considerable
amount of coal and coke have been done away with, at the expense
of power, equal to about 175 h.p. hours, of the average value of
perhaps 65c., and a small amount of coal for melting the lead in the
electrolytic method.
More important, however, is the greater saving of the metal values by
reason of increased yields of gold, silver, lead, antimony and bismuth,
and the freedom of the refined lead from bismuth.
Public-domain text, read in full here on John Shaqi.
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