Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
The tanks are made of 2 in. cedar, bolted together and thoroughly
painted with rubber paint. Any leakage is caught underneath on sloping
boards. Solution is circulated from one tank to another by gravity, and
is pumped from the lowest to the highest by means of a wooden pump. The
22 anodes in each tank together weigh about 3 tons, and dissolve in
from 8 to 10 days, two sets of cathodes usually being used with each
set of anodes. While 300 lb. cathodes can be made, the short-circuiting
gets so troublesome with the spacing used that the loss of capacity is
more disadvantageous than the extra work of putting in and taking out
more plates. The lead sheets used for cathodes are made by depositing
about 1/16 in. metal on paraffined steel sheets in four of the tanks,
which are different from the others only in being a little deeper.
The anodes may contain any or all of the elements, gold, silver,
copper, tin, antimony, arsenic, bismuth, cadmium, zinc, iron, nickel,
cobalt and sulphur. It would be expected that gold, silver, copper,
antimony, arsenic and bismuth, being more electronegative than lead,
would remain in the slime in the metallic state, with, perhaps, tin,
while iron, zinc, nickel and cobalt would dissolve. It appears that tin
stands in the same relation to lead that nickel does to iron, that is,
they have about the same electromotive forces of solution, with the
consequence that they can behave as one metal and dissolve and deposit
together. Iron, contrary to expectation, dissolves only slightly, while
the slime will carry about 1 per cent. of it. It appears from this that
the iron exists in the lead in the form of matte. Arsenic, antimony,
bismuth and copper have electromotive forces of solution more than 0.3
volt below that of lead. As there is no chance that any particle of
one of these impurities will have an electric potential of 0.3 volt
above that of the lead with which it is in metallic contact, there is
no chance that they will be dissolved by the action of the current. The
same is even more certainly true of silver and gold. The behavior of
bismuth is interesting and satisfactory. It is as completely removed by
this process of refining as antimony is. No other process of refining
lead will remove this objectionable impurity so completely. Tin has
been found in the refined lead to the extent of 0.02 to 0.03 per cent.
This we had no difficulty in removing from the lead by poling before
casting. There is always a certain amount of dross formed in melting
down the cathodes; and the lead oxide of this reacts with the tin in
the lead at a comparatively low temperature.
The extra amount of dross formed in poling is small, and amounts to
less than 1 per cent. of the lead. The dross carries more antimony and
arsenic than the lead, as well as all the tin. The total amount of
dross formed is about 4 per cent. Table I shows its composition.
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