Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
_Ore Smelting._—The silver ore from South America (containing antimony
and much silver, together with galena, iron and copper pyrites) is
crushed by rolls and is roasted down from 26 per cent. to 3 per cent.
S in 11 reverberatory furnaces, 70 ft. long and 15 ft. wide (inside
dimensions). It is then mixed with rich galena from Idaho, pyrites
cinder, litharge, copper skimmings, and residues from the desilverizing
process, together with limestone, and is smelted for work-lead and
lead-copper matte in three water-jacketed furnaces, using 12 per cent.
coke, figured on the ore in the charge. Of these furnaces one has 12
tuyeres; it measures 42 × 96 in. in cross-section at the tuyeres, and
6 ft. 3 in. by 8 ft. at the charging level. The hight of charge is 16
ft. The other two furnaces have 16 tuyeres each, their cross-section at
the tuyeres being 44 in. by 128 in., at the charging level 6 ft. 6 in.
by 12 ft., and hight of charge 16 ft. The furnaces are operated at a
blast pressure of 35 oz. per square inch. The temperature of the gases
at the throat is 140 deg. F. (60 deg. C.) measured with a Columbia
recording thermometer, which works very well. These furnaces reduce,
respectively, 100 to 120 and 130 to 140 tons of charge per 24 hours;
they are also used for concentrating roasted matte.
_Copper Refining._—The crude copper is melted in two furnaces of 125
tons aggregate daily capacity, and is molded into anodes by Walker
casting machines. Twenty-six anodes are lifted out of the cooling
vessel at a time, and are taken to the electrolytic plant.
The electrolytic plant comprises two systems, each of 408 vats. The
current is furnished by two dynamos, each giving 4700 amperes at 105
volts. The cathodes remain in the bath for 14 days. The weight of the
residual anodes is 15 per cent.
The anode mud is swilled down into reservoirs in the cellar as at
Chrome (De Lamar Copper Refining Company), is cleaned, dried and
refined in a similar manner.
For melting the cathodes there are two reverberatory furnaces of
capacity for 75 tons per 24 hours. The wire-bars and ingots are cast
with a Walker machine. About 3200 tons of refined copper are produced
per month.
_Copper Sulphate Manufacture._—The lyes withdrawn from the electrolytic
process are worked up into copper sulphate, shot copper being added.
This latter is prepared in a reverberatory furnace from matte obtained
as a by-product in working up the lead. About 200 tons of copper
sulphate are thus produced per month; the process used is the same as
at the Oker works. Lower Harz, Germany. The crystals are rinsed, dried
and packed in strong wooden barrels.
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