Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
The current practice, in many parts of Spain, is to run the same number
of ore-smelting and of matte-smelting furnaces. All the slag and the
raw matte, produced by the ore-smelting furnaces, is re-smelted in the
matte furnaces, together with some dry silver ores. No lead at all is
produced in the matte furnaces, only a matte containing up to 150 oz.
silver per ton and 25 to 35 per cent. of the lead charged on them. This
rich matte is calcined in kilns, and smelted together with the ore
charge.
The ores we smelted were galena ranging from 5 to 83 per cent. lead
and about 250 oz. silver per ton of lead; dry silver ores containing
up to 120 oz. silver per ton, and enough of the Linares carbonates for
keeping the silver below 120 oz. per ton in the lead. The gangue of the
galena was mainly iron carbonate. Most of that ore was hand picked and
of nut size. Machine concentrates with more than 30 per cent. lead or
containing much pyrite were calcined; everything else was smelted raw.
The flux exclusively used, before I came, was carbonate of iron, which,
by the way, was considered a “cure-for-all.” The slag analyses showed:
CaO, below 4 per cent.
FeO, above 45 per cent.
SiO₂, about 30 per cent.
BaO, 5 to 10 per cent.
Al₂O₃, 5 to 10 per cent.
Pb, by fire assay, 0.75 to 2.5 per cent.
Ag, by fire assay, 2 to 3 oz. per ton.
The specific gravity of the slag was about 5, or practically the same
as that of the matte. The output of metallic lead was about 70 per
cent.; of silver, 84 per cent. The working hight of the furnaces—tuyere
level to top of charge—was at that time only 7 ft., and I was told that
it had been still lower before.
To the working hight of the furnaces was added 2 ft., simply by putting
up the charging doors that much. A very good limestone was found just
outside the fence around the plant. Enough limestone was substituted
for the iron carbonate, to keep the lime up to 12 per cent. in the
slag, reducing the FeO to below 35 per cent. and the specific gravity
to below four.
The result of these alterations was an increase in the output of
metallic lead, from 76 to 85 per cent.; of silver from 84 to 90 per
cent.; a comparatively good separation of slag and matte, and a slag
running about 0.5 to 0.75 per cent. Pb and 1.5 oz. Ag per ton.
Owing to the great extent of the gallery, and the consequent good
condensation of the flue dust, the total loss of lead and silver was
much smaller than would be expected; in no case being found above 4 per
cent.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account