Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
_Behavior of Iron._—The output of lead is so dependent upon the
reactions of the iron in the charge that the chief attention may well
be fixed upon that metal as the key to the situation. The success of
the process depends largely upon reducing just the right amount of
iron to throw the lead out of the matte, the remainder of the iron
being reduced only to ferrous oxide and entering the slag. Too much
iron reduced will form a sow in the hearth. Iron is reduced from its
oxides principally by contact with solid incandescent carbon, and by
the action of hot carbon monoxide. Reduction by solid carbon is the
more wasteful, but there is in lead smelting an even more serious
objection to permitting the reduction to be accomplished by that means,
which leads to comparatively hot top and more or less volatilization of
lead. Reduction by carbon monoxide is the ideal condition for the lead
furnace. It means keeping the zone of incandescence low in the charge
column, leaving plenty of room above for the gases to yield up their
heat to, and exercise their reducing power on, the descending charge,
so that by the time they escape they will be well-nigh spent. Their
volume and temperature will be diminished, and the low velocity of
their exit will tend to minimize the loss of lead in fume and flue dust.
The idea that high temperatures in lead blast furnaces should be
avoided is based on a misconception. Temperatures must exist which
are sufficiently high to volatilize all the lead in the charge, if
other conditions permit. A high temperature before the tuyeres means
fast smelting; and fast smelting, under proper conditions, means a
shortening of the time during which the lead is subject to scorifying
and volatilizing influences. A rapidly descending charge, constantly
replenished with cold ore from above, absorbs effectively the heat of
the gases and acts as a most efficient dust and fume collector. In
considering long flues, bag-houses, etc., it should be kept in mind
that the most effective dust collector ought to be the furnace itself.
In the practice of twelve years ago and earlier, particularly when
using mixed coke and charcoal, reduction by carbon was probably the
rule; and the percentage of fuel required was very high. There is good
reason to think we have still much room for improvement along this line
in our average practice of today.
Public-domain text, read in full here on John Shaqi.
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