Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
For many years I have taken great interest in the composition of slags,
and have studied them microscopically and chemically. The conclusion to
which I have been led as regards zinc oxide is, that in a not too basic
slag it is originally mainly, if not wholly, taken up as silicate along
with the other bases. On one occasion, one of my furnaces for several
days produced a slag in which beautiful crystals of willemite were
very abundant, both free in cavities and also imbedded throughout the
mass of solid slag, as shown in thin sections under the microscope. In
the same slag was a large amount of magnetite, all of which contained
a considerable proportion of zinc oxide combined with it. Magnetite
crystals, separated out from the slag and treated with strong acid,
yielded shells of material retaining the form of the original mineral,
rich in zinc oxide; an inter-crystallized zinc-iron spinel, in fact.
I have seen and separated zinc-iron spinels very rich in zinc oxide
from other slags. They have been seen in the slags at Freiberg; and
of course everybody knows the very interesting paper by Stelzner and
Schulze, in which they described the beautiful formations of spinels
and willemite in the walls of the retorts of zinc works.
I think there is thus good ground for concluding that zinc oxide is
slagged off as combined silicate, and that free oxide does not exist
in slags; though zinc oxide does occur in them after solidification,
combined with other oxides, in forms ranging from a zinkiferous
magnetite to a more or less impure zinc-iron, or zinc-iron-alumina
spinel, these minerals having crystallized out in the earlier stages of
cooling.
The microscope showed that the crystals of willemite, mentioned above,
were the first things to crystallize out from the molten slag. The main
constituent was well-crystallized iron-olivine-fayalite.
PART V
LIME-ROASTING OF GALENA
THE HUNTINGTON-HEBERLEIN PROCESS
(July 6, 1905)
It is a fact, not generally known, that the American Smelting and
Refining Company is now preparing to introduce the Huntington-Heberlein
process in all its plants, this action being the outcome of extensive
experimentation with the process. It is contemplated to employ the
process not only for the desulphurization of all classes of lead ore,
but also of mattes. This is a tardy recognition of the value of a
process which has been before the metallurgical profession for nine
years, the British patent having been issued under date of April
16, 1896, and has already attained important use in several foreign
countries; but it will be the grandest application in point of
magnitude.
Public-domain text, read in full here on John Shaqi.
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