Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
When the Huntington-Heberlein process was first described, it did not
even appear a simplification of the ordinary roasting process, but
rather a complication of it. The process attracted comparatively little
attention, and was indeed regarded somewhat with suspicion. This was
largely due to the policy of the company which acquired the patent
rights in refusing to publish the technical information concerning it
that the metallurgical profession expected and needed. The history of
this exploitation is another example of the disadvantage of secrecy
in such matters. The Huntington-Heberlein process has only become
thoroughly established as a new and valuable departure in metallurgy, a
departure which is indeed revolutionary, nine years after the date of
the original patent. In proprietary processes time is a particularly
valuable element, inasmuch as the life of a patent is limited.
From the outset the explanation of Huntington and Heberlein as to the
reactions involved in their process was unsatisfactory. Professor
Borchers points out clearly that their conception of the formation of
calcium peroxide was erroneous, and indicates strongly the probability
that the active agent is calcium plumbate. It is very much to be
regretted that he did not go further with his experiments on this
subject, and it is to be hoped that they will be taken up by the
professors of metallurgy in other metallurgical schools. The formation
of calcium plumbate in the process was clearly forecasted, however, by
Carmichael and Bradford in their first patent specification; indeed,
they considered that the sintered product consisted largely of calcium
plumbate.
Even yet, we have only a vague idea of the reactions that occur in
these processes. There is undoubtedly a formation of calcium sulphate,
as pointed out by Borchers and Savelsberg; but that compound is
eventually decomposed, since it is one of the advantages of the
lime-roasting that the sintered product is comparatively low in
sulphur. Is it true, however, that the calcium eventually becomes
silicate? If so, under what conditions is calcium silicate formed? The
temperature maintained throughout the process is low, considerably
lower than that required for the formation of any calcium silicate by
fusion.
Moreover, it is not only galena which is decomposed by the new
method, but also blende, pyrite and copper sulphides. The process is
employed very successfully in the treatment of Broken Hill ore that is
rather high in zinc sulphide, and it is also to be employed for the
desulphurization of mattes. What are the reactions that affect the
desulphurization of the sulphides other than lead?
There is a wide field for experimental metallurgy in connection with
these new processes. The important practical development is that they
do actually effect a great economy in the reduction of lead sulphide
ores.
THE NEW METHODS OF DESULPHURIZING GALENA[18]
BY W. BORCHERS
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