Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
It is, however, quite certain that Huntington and Heberlein, in the
theoretical explanation of the process, failed to understand the most
important reactions. Their attributing the effect to the formation and
action of calcium peroxide affords a sad case of _a priori_ assumption
devoid of any shred of evidence. As Professor Borchers points out,
calcium peroxide, so difficult to produce and so unstable when formed,
is an absolute and absurd impossibility under the conditions in
question. Probably many rubbed their eyes with astonishment on reading
that part of the patent on its first appearance, and hastened to look
up the chemical authorities to refresh their minds, lest something as
to the nature of calcium peroxide might have escaped them.
Fortunately the patent law is such that there was no danger of a really
good and sound invention being invalidated by a wrong theoretical
explanation by its originators. But, nevertheless, it was a misfortune
that the inventors did not understand their own process. Had they
known, they could have added a few more words to their patent-claims
and rendered the Carmichael patent an impossibility.
Professor Borchers appears to consider that the active agent in the new
process is calcium plumbate. That this compound may play a part at some
stage of the process may be true; this long ago suggested itself to
some others. We may yet expect to hear that the experiments undertaken
by Professor Borchers himself, and by others at his instigation (in
which calcium plumbate is separately prepared and then brought into
action with lead sulphide), have given good results. But it does not
appear so far that there is any real proof that calcium plumbate is
formed in the Huntington-Heberlein or other similar processes; and it
is difficult to see at what stage or how it would be produced under the
conditions in question. This is a point which research may clear up,
but it should not be taken for granted at this stage. Indeed, it seems
to me that the results obtained may be fairly well explained without
calling calcium plumbate into play at all.
Of course the action of lime in contact with lead sulphide excited
interest many years before the new process came into existence. My own
attention to it dates back more than a dozen years before that time (I
was in charge of works where I found the old “Flintshire process” still
in use).
Percy pointed out, in his work on lead smelting, that on the addition
of slaked lime to the charge, at certain stages, to “stiffen it up,”
the mixture could be seen to “glow” for a time. When I myself saw this
phenomenon, I commenced to make some observations and experiments.
Also (as others probably had done), I had observed that charges of lead
with calcareous gangue are roasted more rapidly and better than others,
and to an extent which could not be wholly explained by simple physical
action of the lime present.
Public-domain text, read in full here on John Shaqi.
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